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    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 122 (1991), S. 915-920 
    ISSN: 1434-4475
    Keywords: Barium ; Silver ; Mercury ; Oxide ; High-pressure synthesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary BaAg2Hg2O4 was prepared by an oxygen high-pressure technique. Single crystal X-ray investigations led to tetragonal symmetry, space group D 4h 3 − P4/nbm;a=6.793;c=7.086 Å;Z=2. Hg2+ and Ag+ show dumb-bell like coordination by oxygen whereas Ba2+ ions are surrounded by 8 O2− forming distorted cubes. The BaO8-polyhedra distortions are discussed in respect to the incorporation of Hg2+ ions into the BaAg2O 4 2− network.
    Type of Medium: Electronic Resource
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