ISSN:
1434-4475
Keywords:
2-Methoxymethylpyrrolidine
;
Carbon disulfide
;
Pyrrolidine-1-dithiocarboxylates
;
Crystal structure
;
Diastereomers
;
HPLC
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Formation of the 2-methoxymethyl-pyrrolidine-1-dithiocarboxylates2–4 and alkylation of2 and3 were studied. Enantiomeric and diastereomeric derivatives of4, the preparation of diastereomeric mixtures of4 by alkylation of3 in the presence of strong bases, and formation of6 by phase transfer alkylation of2 are described. The two enantiomers of 2-(4-bromophenyl)-2-oxo-ethyl 2-methoxymethylpyrrolidine-1-dithiocarboxylate2 have been characterized by X-ray analysis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00807097
Permalink