ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The title reaction is investigated for total angular momentum I=0 using a semiclassical coupled wave packet method where the Smith–Whitten-type hyperspherical angles θ and cursive-phi are treated quantally, and the hyperspherical radius ρ is treated classically. The wave function is expanded over an electronic basis set which includes 28 states. The diabatic potential energy surfaces are determined by DIMZO calculations. Probabilities for reaction, charge transfer, collision induced dissociation, dissociative charge transfer, and fine structure transitions are obtained in the energy range 0.3 eV≤E≤30 eV. A comprehensive analysis of the reaction mechanisms is presented. © 1996 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.471156
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