ISSN:
1572-8927
Keywords:
Potassium tetraphenylborate
;
solubility
;
activity coefficient
;
ionic association
;
standard Gibbs energy of transfer
;
medium effect
;
solvation energy
;
microscopic interactions
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Solubilities of potassium tetraphenylborate in water, methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-octanol at 15, 25, 35, 45, 55°C have been determined by spectrophotometry. The standard Gibbs energy of transfer of potassium tetraphenylborate form water to straightchain n-alkanols and the medium effect of potassium tetraphenylborate from 15 to 55°C have been calculated. Furthermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of potassium tetraphenylborate is calculated and discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01004480
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