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  • 1
    ISSN: 1045-4861
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The need for alternatives to autogenous bone grafts is widely recognized. This study compared the torsional strength of canine femora 1 year after grafting with one of three forms of a collagen/hydroxyapatite/tricalcium phosphate bone grafting material (COLLAGRAFT15), autogenous bone, or no graft. The groups were compared to each other and to the unoperated contralateral femora. Results of torsional testing were evaluated for torsional strength, torsional displacement, total energy to fracture and White fracture mode. Data analysis showed lower torsional strength of the operated vs. unoperated femora with the exception of morsellized COLLAGRAFT15 material, which had higher strength. However, the only difference in the operated groups was that the morsellized COLLAGRAFT15 had greater strength than several groups including the autogenous bone group. There was no difference found in angular displacement between any of the groups. However, there was a difference in the energy to fracture in both strip forms of the COLLAGRAFT15. The final conclusion is that in this model, grafting with COLLAGRAFT15 provided torsional properties at one year postoperatively at least equivalent to autogenous bone. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The behavior of polymer - solvent systems has been studied as a function of hydrostatic pressure to 3000 atm. The swelling of crosslinked neoprene and crosslinked Hevea has been studied in several solvents, and the temperature of phase separation of polystyrene in cyclohexane has been determined. These measurements permit an indirect evaluation of the volume of mixing that is felt to have advantages over the direct method due to the small magnitude of the effect in polymer systems. In all of the cases studied by the swelling technique, the volume of mixing is negative and tends to be greater in magnitude the better the solvent. For the very poor solvent - polymer system studied by the precipitation technique, a small positive value is obtained. In addition, the compressibility of swollen polymers is compared with that expected from an assumption of additivity and found to be much smaller. These phenomena are presumably the result of a more tightly packed liquid structure within the polymer network. This explanation suggests that the descriptions of the volume of mixing in terms of the apparent specific volume, while certainly formally correct, may be misleading physically. An attempt to relate the observations on these systems to a theory involving a power series expansion in terms of the solvent fugacity was unsuccessful due to the slow convergence of the series.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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