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  • Polymer and Materials Science  (1)
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  • Polymer and Materials Science  (1)
  • Physics  (1)
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    Electronic Resource
    Electronic Resource
    Cage effects in recombination of allyl radicals in irradiated polyethylene (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 983-989 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A cage model has been presented to describe the kinetics of recombination of radicals in solid polymer. The theory includes Torrey's treatment for jump diffusion and radiative boundary condition in the diffusion equation to account for the hindrance to the diffusion of macroradicals and the finite cage process of recombination reaction, respectively. The result has been applied to the interpretation of data on the decay of allyl radical in irradiated polyethylene.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190607
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