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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 180 (1979), S. 633-647 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Bromodifluoroacetaldehyde (5) was prepared from methyl bromodifluoroacetate (4) by reduction with lithium aluminium hydride. 4 was in turn prepared by bromination of chlorotrifluoroethylene (1) and treatment of the resulting 1,2-dibromo-1-chlorotrifluoroethane (2) with fuming H2SO4 and HgO. 5, properly purified, could be polymerized with anionic and cationic initiators to poly[oxy-2-(bromodifluoro)ethylidene] (12). Certain initiators produce partially or entirely amorphous soluble 12 of relatively low molecular weight. Most polymers, however, are insoluble, crystalline, and presumably isotactic. Thermal vacuum degradation of the polymers 12 gave monomer 5 in essentially quantitative yield. The thermal stability of polymers can significantly be improved by endcapping or treating with agents which replace unstable end groups. The ceiling temperature of the polymerization of 5 was determined to be +48°C. 5 was copolymerized with trichloroacetaldehyde with cationic or anionic initiators to copolymers containing predominantly units of 5. 5 could also be copolymerized with phenyl isocyanate to a polymer containing oxycarbamido linkages.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 2001-2006 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Nitric acid digestion studies of ethylene-vinyl acetate copolymers indicated that copolymers containing identical amounts of vinyl acetate but varying in melt index differed in crystallinity. These results were confirmed by x-ray analysis. The differences in crystallinity were interpreted as showing a variation in the degree of short-chain branching in the polyethylene segments of the copolymer chain. This variation was correlated with the conditions of synthesis.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1123-1135 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chlorodifluoroacetaldehyde has been prepared by lithium aluminum hydride reduction of methyl chlorodifluoroacetate. Purified chlorodifluoroacetaldehyde was polymerized to crystalline, insoluble polychlorodifluoroacetaldehyde or to a mixture of amorphous polymer soluble in organic solvents and insoluble polymer, depending on polymerization conditions and type and amount of initiators. The polymer, particularly the soluble fraction, could be end-capped by acetylation to improve the thermal stability of the initially unstable polymer. The thermal degradation of polymer prepared by various techniques has been studied before and after acetylation and the stability was compared to that of other polyhaloacetaldehydes. Chlorodifluoroacetaldehyde was copolymerized with other haloacetaldehydes and with phenyl isocyanate.
    Additional Material: 5 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 16 (1991), S. 255-265 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The quasi-static compaction behavior of a number of single- and double-base ball propellants has been investigated to determine the effect of nitroglycerin (NG) content. Simultaneous measurements were obtained of axial applied and transmitted forces, circumferential strain, and porous bed displacement, resulting in the calculation of axial average solid stress and radial stress as a function of porous bed consolidation. Five Olin ball propellants designated as WC140, TS3660, TS3659, Winchester #231, and TS3661 in order of increasing NG content, were compacted. Their NG concentrations ranged from 0 to ∼35 wt%. The most significant effects of increased NG content were to decrease the various axial and radial stress levels present at constant degree of bed consolidation and to increase the coefficient of kinetic friction at the porous bed/mold wall interface. Microscopic examination of recovered samples that had been compacted revealed that extensive plastic deformation occurred in the absence of particle fracture.
    Additional Material: 11 Ill.
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