ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Two nonlinear dihydrazides, namely 1,2-bis(3-hydrazinocarbonylphenoxy)ethane and bis[2(3-hydrazinocarbonylphenoxy)ethyl] ether, were synthesized by the acylation reaction of hydrazine hydrate with the corresponding aromatic esters and were characterized by IR, 13C-NMR, and mass spectroscopy. These dihydrazides were each polycondensed with dianhydrides, benzophenonetetracarboxylic dianhydride (BTDA), and pyromellitic dianhydride (PMDA) to obtain poly(amic acid) with ηinh 0.60-0.85 dL/g in dimethylacetamide solution. These poly(amic acid)s were soluble in polar aprotic solvents like dimethylacetamide (DMAc), dimethyl formamide (DMF) and could be cast into transparent, tough, and flexible films that were cyclodehydrated to obtain amorphous, thermally stable polyamide-imides. The polymers were characterized by IR spectroscopy, X-ray diffraction, and thermogravimetric analysis.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1990.070400720
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