ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The fluidization technique was applied for the surface modification of powder by plasma, and whether the technique was a practically useful one in the surface modification of powder or not was discussed. Polyethylene powder was used as a specimen to be modified. The oxygen plasma treatment of the polyethylene powder in the fluidized state showed a capability that the surface of the powder was changed from hydrophobic to hydrophilic. The contact angle of water for the treated powder surface was 51°C, which was estimated from the dynamic wicking data. The hydrophilic surface modification of the polyethylene powders in the fluidized bed required the operation of the plasma treatment for at least 3 h. The requirement of the plasma operation for long time rises mainly from large surface area of the powder. The oxygen plasma treatment led to the formation of oxygen functionalities including C = O and C(O)—O— groups at the outermost layer of the powder. The concentration of the C=O and C(O)—O— functionalities reached 10 and 6% of the total carbon elements being in the XPS sampling depth, respectively. From these results we conclude that the fluidization technique is a useful manner in the surface modification of powder by plasma.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1992.070460405
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