ISSN:
1040-0397
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The electron transfer between excited-state 9,10-anthracenedione (325 nm) and sodium tetraphenylborate (tetraphenylboron sodium) in acetonitrile solution is shown to form the radical anion of 9,10-anthracenedione together with the BPh4· radical. The latter is known to decompose to biphenyl and other Products. A new channel electrode methodology is developed and characterized to deduce the mechanism of the reaction and to quantify its kinetics.
Zusätzliches Material:
8 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/elan.1140030308
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