ISSN:
0570-0833
Keywords:
Polychloroamines
;
Chloroamines
;
Amines
;
Chlorination
;
Synthetic methods
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Highly chlorinated amine derivatives can be prepared by the high-temperature chlorination of amines and amine derivatives. Essential for the success of this reaction is an adequate temperature control suited to the constitution of the amines. In many cases the chlorination products achieve stability by cleavage reactions with formation of the imidic acid chloride or isocyanide dichloride grouping. Cyclic compounds are formed under special conditions. The chlorination process described can be used to obtain e.g. polychloroaryl and polychloroalkyl isocyanide dichlorides, polychloroaryl and polychloroalkyl imidic acid chlorides, and polychloroheterocyclic compounds.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196808561
Permalink
