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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 22 (1984), S. 707-719 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The sorption and diffusion of toluene vapor at 30°C in polypropylene with draw ratios from 1 to 18 have been studied. Drawing leads to the transformation of the initially spherulitic material into the fibrous structure, with many taut tie molecules lying mainly on the outer boundary of the microfibrils. The free volume and hence the sorption sites are thereby reduced, and the microfibrils become less and permeable as the draw ratio increases. As a result, the equilibrium concentration and the zero-concentration diffusion coefficient drop by factors of 4 and 30, respectively. The diffusion coefficient increases exponentially with toluene concentration but the concentration dependence becomes weaker with increasing draw ratio, indicating that the severely constrained chain segments in the drawn samples have much less freedom to mix with penetrant molecules. Annealing relaxes the tie molecules and thus restores the sorption and diffusion properties to values corresponding to completely relaxed amorphous component, i.e., to values even higher than those of the undrawn but quenched material.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 557-563 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The rotational mobility of nitroxide radicals in polypropylene samples with draw ratios varying from 1 to 18 has been studied between 30 and 110°C by the ESR technique. The drop in the rotational frequency with increasing orientation correlates very well with the behavior of various other measures of molecular mobility such as organic vapor sorption, proton spin-spin relaxation times from NMR, and dynamic mechanical loss factor. This implies that each of these parameters is a good indicator of the amount of free volume in the amorphous regions. Annealing at high temperature relaxes the amorphous chain segments, thereby increasing the spin-probe rotational frequency in the drawn samples to values even higher than that in the quenched isotropic material.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2019-07-13
    Description: The overall goal of our NASA Theory Program was to study the coupling, time delays, and feedback mechanisms between the various regions of the solar-terrestrial system in a self-consistent, quantitative manner. To accomplish this goal, it will eventually be necessary to have time-dependent macroscopic models of the different regions of the solar-terrestrial system and we are continually working toward this goal. However, with the funding from this NASA program, we concentrated on the near-earth plasma environment, including the ionosphere, the plasmasphere, and the polar wind. In this area, we developed unique global models that allowed us to study the coupling between the different regions. These results are highlighted in the next section. Another important aspect of our NASA Theory Program concerned the effect that localized 'structure' had on the macroscopic flow in the ionosphere, plasmasphere, thermosphere, and polar wind. The localized structure can be created by structured magnetospheric inputs (i.e., structured plasma convection, particle precipitation or Birkland current patterns) or time variations in these input due to storms and substorms. Also, some of the plasma flows that we predicted with our macroscopic models could be unstable, and another one of our goals was to examine the stability of our predicted flows. Because time-dependent, three-dimensional numerical models of the solar-terrestrial environment generally require extensive computer resources, they are usually based on relatively simple mathematical formulations (i.e., simple MHD or hydrodynamic formulations). Therefore, another goal of our NASA Theory Program was to study the conditions under which various mathematical formulations can be applied to specific solar-terrestrial regions. This could involve a detailed comparison of kinetic, semi-kinetic, and hydrodynamic predictions for a given polar wind scenario or it could involve the comparison of a small-scale particle-in-cell (PIC) simulation of a plasma expansion event with a similar macroscopic expansion event. The different mathematical formulations have different strengths and weaknesses and a careful comparison of model predictions for similar geophysical situations provides insight into when the various models can be used with confidence.
    Keywords: SOLAR PHYSICS
    Type: NASA-CR-190082 , NAS 1.26:190082
    Format: application/pdf
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  • 4
    Publication Date: 2019-07-12
    Description: Electrostatic waves produced by the interaction of the ion cloud with the solar wind are analyzed in order to explain the shocklike noise detected by the Ion Release Module instruments during the Active Magnetospheric Particle Tracer Explorers solar wind ion releases. The results indicate that the shocklike noise can be generated by two instabilities, an ion-electron instability that occurs for waves propagating parallel to the solar wind velocity and an ion-ion instability that occurs for waves propagating at a large angle to the solar wind direction. Both instabilities give high growth rates for both the lithium and barium releases. The calculated results agree with the observed ones in all main features. In the earlier stage of the ion cloud expansion, both instabilities are likely to occur, while in the later stage the ion-ion instability is more likely to occur.
    Keywords: SOLAR PHYSICS
    Type: AD-A184312 , Journal of Geophysical Research (ISSN 0148-0227); 92; 2555-255
    Format: text
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