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Atropisomeric Binaphthalene-Core Phosphacyclic Derivatives in Coordination Chemistry and Homogeneous Catalysis (1997)

Gladiali, Serafino ; Fabbri, Davide

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 543-554

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ISSN: 0009-2940

Keywords: Phosphorus heterocycles ; Binaphthophosphole ; Atropisomerism ; Binaphthophosphepine ; Hydroformylations ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Binaphthophospholes and binaphthophosphepines have recently been synthesized. These are the first representatives of a new class of chiral ligands that include within the same structure an endocyclic phosphorus donor, a local C2 symmetry and an axially chiral core. In this review we discuss the synthesis, chemical behaviour and first applications in asymmetric catalysis of these novel derivatives.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971300503

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