ISSN:
0887-624X
Schlagwort(e):
polyethers
;
differential scanning calorimetry
;
crosslinking kinetics
;
PECH-PEO
;
thermosets
;
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The epichlorohydrin-ethyleneoxide copolymer is modified with 10-undecenoate and 4-pentenoate moieties in order to obtain thermosets by cross-linking through their double bonds. These polymers are then characterized using NMR, IR, chlorine elemental analyses, X-ray powder diffraction, DSC, TGA, and viscosimetric measurements. Because the thermal crosslinking reaction overlaps in all cases with degradation processes, a free radical source (dicumyl peroxide) is necessary. The Arrhenius kinetic parameters are determined by DSC, using Ozawa and Kissinger expressions. Finally, the quality of cured materials is tested by TGA. © 1995 John Wiley & Sons, Inc.
Zusätzliches Material:
4 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pola.1995.080330607
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