ISSN:
0894-3230
Keywords:
calixarenes
;
bipyridine
;
lanthanides
;
luminescence
;
preorganization
;
solvent effect
;
Chemistry
;
Theoretical, Physical and Computational Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
---Based on MD simulations, the structures of Eu3+ and EuCl3 complexes of bipyridine-substituted calixarenes in different environments (in vacuo and in acetonitrile and water solutions) were modelled. The data account for the differences in their luminescence properties. The role of the calixarene platform, preorganization of the ligands, and an explicit account of counterions in different environments are analysed. © 1997 John Wiley & Sons, Ltd.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
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