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Lanthanum isopropoxide catalyzed addition of activated nucleophiles to imines (1995)

Yamamoto, Yoshinori ; Fukui, Hiroyuki ; Honda, Yoshihiro

New York, NY [u.a.] : Wiley-Blackwell

Applied Organometallic Chemistry 9 (1995), S. 467-471

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ISSN: 0268-2605

Keywords: lanthanum isopropoxide ; imines ; methylmalonitrile ; methyl 2-cyanopropanoate ; α-imino ester ; N-toluenesulfonylimine ; N-(4-methoxycarbonylphenyl)imine ; addition to imines ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The addition of certain activated nucleophiles to activated imines is catalyzed by lanthanum isopropoxide. As activated nucleophiles, methylmalononitrile and methyl 2-cyanopropanoate can be utilized. Imines having an electronwithdrawing group either at the carbon or at the nitrogen atom of the C=N double bond can be used; for example N-toluenesulfonylimines, N-(4-methoxycarbonylphenyl)imines and α-imino esters.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aoc.590090515

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