ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reacted with phosphorous acid under reduced pressure, the linear 1,ωdiols (ω= 3 to 8) yield a mixture of the corresponding phosphorous diprimary diesters H,2O2-R-OPO2, H2, and ω-hydroxy-1-alkyl monoesters. Cyclohexane-1,4-diol reacts in the same manner. The linear diols with ω = 2, 9, 10 or 32, as well as cyclohexane- l12-diol, yield the phosphorous monoesters exclusively. Halogenated alcohols, cyclohexanol, and glycerol, reacted with phosphorous acid, yield the corresponding phosphorous monoesters. Phosphorous monoesters and diprimary diesters are stable in aqueous solutions between pH 3 and pH 9, but are very quickly hydrolized in strongly acidic or alka- line solutions.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19640470143
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