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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 24 (2000), S. 277-291 
    ISSN: 1573-0417
    Keywords: varves ; anoxia ; sediments ; Soppensee ; carbon cycle ; oxygen cycle
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We analyzed seasonally aggregated observations of temperature, conductivity, dissolved oxygen and dissolved inorganic carbon from Soppensee (District of Lucerne, Switzerland) for the yrs 1980 to 1993. Holomictic Soppensee is characterized by a strong summer stratification with a thin epilimnion separated from an anoxic hypolimnion by a strong pycnocline formed by thermal and chemical gradients. A vertical one-dimensional model was developed to simulate the observed seasonal cycles of carbon and oxygen. The processes of net community production, mineralization of organic matter, precipitation and dissolution of calcite, gas exchange, in- and outflow, sedimentation and vertical eddy diffusion are included. According to the model, the annual net community production is estimated to about 110 g C m-2 yr-1 and the annual net primary production to about 330 to 440 g C m-2 yr-1, which is a typical value for eutrophic lakes. A mass balance of the carbon cycle indicates that most of the inflow comes from groundwater which is super-saturated with respect to atmospheric CO2. Therefore the surface waters exhibit a large capacity for calcite precipitation. The results of the model are used to constrain the conditions that favor the formation of varved sediments in Soppensee during thousands of yrs. Model calculations show that the deep waters would still turn anoxic even if the sedimentation rate of organic matter were decreased to 25%. Several physical factors such as biogenic stabilization of the deep waters due to calcite dissolution and low input of wind energy are responsible for the long term anoxia in Soppensee.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Cell & tissue research 188 (1978), S. 481-490 
    ISSN: 1432-0878
    Keywords: Fat body ; Cockroach ; Reproductive cycle ; Ultrastructure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The central fat body of the ovoviviparous cockroach Nauphoeta cinerea was studied during the first reproductive cycle of the female by means of light microscopy, autoradiography and electron microscopy. Comparative studies in larval stages were also undertaken. The fat body of Nauphoeta contains a large amount of lipid droplets and the remaining cytoplasm is very scarce. The cytological cyclicity of the fat body is consistent with the known biochemical rhythms of vitellogenin production. The proteosynthetic apparatus appears about 3 days after imaginal ecdysis, along with vitellogenin. The ribosomal endoplasmic reticulum (RER) shows a tremendous increase by the 7th day of the first cycle. The most active period of vitellogenin production lasts from day 7 to day 12. The proteosynthetic apparatus then returns to an inactive stage and disappears. This inactive condition lasts to the end of the gestation period. The autoradiographic results are consistent with the cytological features.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 62 (1979), S. 2661-2672 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Conjugated cyclic divinyl ketones containing fifteen and seventeen membered rings have been prepared in a single step by condensation of 1,3-bis (dimethylphosphono)-2-propanone (10) with the dialdehydes 14, 17, 20, and 42 in the presence of hydrogencarbonate in aqueous t-butyl alcohol at reflux without using high dilution techniques. The more highly unsaturated aldehydes give better yields and ketones 34 and 36, or mixtures of the two, were transformed to muscone (1) and Exaltone® by standard procedures. Civetone (2) was prepared by hydrogenation of 43 in pyridine solution. Dienone 29 appears to be the first α, β-unsaturated ketone in which one of the β-vinyl proton resonates at higher field than the corresponding α-proton.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 72 (1989), S. 996-1000 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (±)-Ambrox (10), the racemic form of (-)-Ambrox®, the commercially most important ambergris odorant has been synthesized from a readily available bicyclic keto ester in five steps. The racemic ether retains the characteristic scent of fine-quality ambergis, and the odor threshold of the racemate and the (-)-enantiomer prepared from natural sclareol were found to be essentially identical.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 54 (1971), S. 1767-1776 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The odor principle β-damascenone and its isomer α-damascenone have been prepared by treatment of the corresponding ethyl safranates with excess allyl lithium followed by alkoxide catalyzed isomerization of the resulting products with β, γ-unsaturated ketonic side chains. Addition of allyltriphenylphosphorane (preferably prepared from allyltriphenylphosphonium chloride) rather than the propenyl isomer to ethyl α-isopropylidene-acetoacetate produced ethyl α-safranate. This represents a new, potentially general method for the synthesis of functionalized cyclohexadienes.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Sinensal, a flavor constituent of the Chinese orange, has been synthesized from myrcene by a four-step sequence of chemical operations.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird ein Verfahren beschrieben, das durch Reduktion von Vitamin A-Säureester mit Lithiumaluminiumhydrid ohne weitere Reinigung Hochkonzentrate von Vitamin A mit 55-75% Gehalt liefert. Wird von einem über die freie Vitamin A-Säure gereinigten Ester ausgegangen, so kann die Reinheit im Rohprodukt auf 95% gesteigert werden. Die Hochkonzentrate (C20-Alkohol und Acetat) wurden durch Analyse, UV.-Spektrum, Carr-Price-Reaktion und biologische Auswertung charakterisiert; das Acetat krystallisierte spontan.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 415 (1918), S. 291-337 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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