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Octanuclear Bis(triple-helical) Metal(II) Complexes (1998)

Saalfrank, Rolf W. ; Löw, Norbert ; Trummer, Stefan ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 559-563

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ISSN: 1434-1948

Keywords: Metal(II) complexes ; Octanuclear complexes ; Supramolecular chemistry ; Zinc ; Cadmium ; Manganese ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reaction of H2L1 and H2L2 with divalent metal ions leads to octanuclear bis(triple-helical) metal(II) complexes of the general composition [Zn8O2L26] (3) and [M8O2L16] (4: M = Cd2+; 5: M = Mn2+). NMR studies of the diamagnetic cadmium complex 4c show six equivalent ligands. Unambiguous characterisation of 5b was achieved by X-ray crystallographic analysis.

Type of Medium: Electronic Resource

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