ISSN:
1434-1948
Keywords:
Polyion aggregates
;
Crystal structure
;
Density functional theory calculations
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The structure determination of the lipophilically wrapped cluster {[Al2Li4O18](C36H44)}∞, a novel material crystallized from a mixture of [(C2H5)3Al]2, nBuLi, and catechol in DME solution, reveals five-coordinate Al++ and Li+ centers. According to density functional theory calculations, the eight negative charges are well-delocalized over the oxygen-rich framework.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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