ISSN:
1572-8757
Schlagwort(e):
silicalite-1
;
adsorption
;
TEOM
;
alkanes
;
isosteric heat
;
adsorption entropy
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Physik
,
Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
Notizen:
Abstract The equilibrium adsorption of the light alkanes methane, ethane, propane, n-butane, and i-butane in silicalite-1 has been investigated using the TEOM technique. Either a conventional or a dual-site Langmuir isotherm appropriately describes the equilibrium data. Good agreement with the literature data determined by other techniques indicates the TEOM is a reliable technique. The adsorption of i-butane in silicalite-1 reveals the discrete preferential molecular siting, implying a discrete-dual-structural heterogeneity for light alkanes in silicalite-1.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1008969518892
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