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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 61 (1990), S. 161-178 
    ISSN: 1572-9613
    Keywords: Critical wetting ; Ising model ; Monte Carlo simulations ; finite-size scaling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The Ising square lattice with nearest-neighbor exchangeJ〉0 and a free surface at which a boundary magnetic fieldH 1 acts has a second-order wetting transition. We study the surface excess magnetization and the susceptibility ofL×M lattices by Monte Carlo simulation and probe the critical behavior of this wetting transition, applying finite-size scaling methods. For the cases studied, the results are not consistent with the presumably exactly known values of the critical exponents, because the asymptotic critical region has not yet been reached. Implication of our results for critical wetting in three dimensions and for the application of the present model to adsorbed wetting layers at surface steps are briefly discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 92 (1998), S. 57-100 
    ISSN: 1572-9613
    Keywords: Mean-field Potts glass ; orientational glass ; infinite range interactions ; Monte Carlo simulations ; finite-size scaling ; self-averaging ; first-order transition without latent heat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The p-state mean-field Potts glass with bimodal bond distribution (±J) is studied by Monte Carlo simulations, both for p = 3 and p = 6 states, for system sizes from N = 5 to N = 120 spins, considering particularly the finite-size scaling behavior at the exactly known glass transition temperature T c. It is shown that for p = 3 the moments q (k) of the spin-glass order parameter satisfy a simple scaling behavior, $$q^{(k)} \alpha N^{--k/3} \tilde f_k \{ N^{1/3} (1--T/T_c )\} ,{\text{ }}k = 1,2,3,...,\tilde f_k $$ being the appropriate scaling function and T the temperature. Also the specific heat maxima have a similar behavior, $$c_V^{\max } \alpha {\text{ }}const--N^{--1/3} $$ , while moments of the magnetization scale as $$m^{(k)} \alpha N^{--k/2} $$ . The approach of the positions T max of these specific heat maxima to T c as N → ∞ is nonmonotonic. For p = 6 the results are compatible with a first-order transition, q (k) → (q jump)k as N → ∞ but since the order parameter q jump at T c is rather small, a behavior q (k) ∝ N -k/3 as N → ∞ also is compatible with the data. Thus no firm conclusions on the finite-size behavior of the order parameter can be drawn. The specific heat maxima c V max behave qualitatively in the same way as for p = 3, consistent with the prediction that there is no latent heat. A speculative phenomenological discussion of finite-size scaling for such transitions is given. For small N (N ≤15 for p = 3, N ≤ 12 for p = 6) the Monte Carlo data are compared to exact partition function calculations, and excellent agreement is found. We also discuss ratios $$R_x \equiv [(\langle X\rangle _T - [\langle X\rangle _T ]_{{\text{av}}} )^2 ]_{{\text{av}}} /[\langle X\rangle _T ]_{{\text{av}}}^2 $$ , for various quantities X, to test the possible lack of self-averaging at T c.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 95 (1999), S. 1045-1068 
    ISSN: 1572-9613
    Keywords: polymer mixtures ; concentration profiles ; Cahn—Hilliard theory ; capillary wave Hamiltonian ; self-consistent field theory ; Monte Carlo simulations ; wetting
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A symmetric binary mixture (A, B) below its critical temperature T c of unmixing is considered in a thin-film geometry confined between two parallel walls, where it is assumed that one wall prefers A and the other wall prefers B. Then an interface between the coexisting unmixed phases is stabilized, which (above the wetting transition temperature) occurs in the center of the film for an average concentration of c=1/2. We consider how the concentration profile c(z) across the thin film depends on the film thickness D. By Monte Carlo simulation of a lattice model for a polymer mixture it is shown that for relatively small D the width of the interface scales like w ∝ D, while for larger D a crossover to a behavior w ∝ $$\sqrt D $$ occurs. This behavior is explained by phenomenological theories: it is shown that the behavior at small D can be understood by a suitable extension of the Cahn—Hilliard “gradient-square”-type theory, while the behavior for large D can be traced back to the behavior of capillary waves exposed to a short-range potential by the walls. Corrections due to fast concentration variations, as they occur in the strong-segregation limit of a polymer mixture, can be accounted for by self-consistent field theory. Subtle problems occur, however, with respect to the proper combination of these theories with the capillary wave approximation, particularly at intermediate values of D.
    Type of Medium: Electronic Resource
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