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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Authors, 2006. This is the author's version of the work. It is posted here by permission of National Academy of Sciences for personal use, not for redistribution. The definitive version was published in Proceedings of the National Academy of Sciences of the United States of America 103 (2006): 13570-13574, doi:10.1073/pnas.0601304103.
    Description: Marine hydrocarbon seepage emits oil and gas, including methane (~30 Tg CH4/year), to the ocean and atmosphere. Sediments from the California margin contain preserved tar, primarily formed via hydrocarbon weathering at the sea surface. We present a record of variation in the abundance of tar in sediments for the past 32ky, providing evidence for increases in hydrocarbon emissions prior to and during Termination IA (16-14 ka) and again over Termination IB (11-10 ka). Our study provides the first direct evidence for increased hydrocarbon seepage associated with deglacial warming via tar abundance in marine sediments, independent of previous geochemical proxies. Climate-sensitive gas hydrates may modulate thermogenic hydrocarbon seepage during deglaciation.
    Description: This work has been supported by the U.S. National Science Foundation (OCE-0242041, Kennett; OCE-0447395, Valentine; IIS-0430835, Reddy) and UC Santa Barbara (Graduate Dissertation Fellowship to T. Hill).
    Keywords: Quaternary climate ; Paleoclimate ; Hydrocarbon ; Methane
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: 2373422 bytes
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 34 (2007): L22603, doi:10.1029/2007GL031344.
    Description: Large quantities of natural gas are emitted from the seafloor into the stratified coastal ocean near Coal Oil Point, Santa Barbara Channel, California. Methane was quantified in the down current surface water at 79 stations in a 280 km2 study area. The methane plume spread over an area of ~70 km2 and emitted on the order of 5 × 104 mol d−1 to the atmosphere. A monthly time series at 14 stations showed variable methane concentrations which were correlated with changing sub-mesoscale surface currents. Air-sea fluxes estimated from the time series indicate that the air-sea flux derived for the 280 km2 area is representative of the daily mean flux from this area. Only 1% of the dissolved methane originating from Coal Oil Point enters the atmosphere within the study area. Most of it appears to be transported below the surface and oxidized by microbial activity.
    Description: The research was supported by the University of California Energy Institute and the National Science Foundation (OCE 0447395).
    Keywords: Air-sea flux ; Shallow marine seep ; Methane
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/postscript
    Format: application/pdf
    Format: text/plain
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