ISSN:
0044-2313
Keywords:
Metallocene dihalides
;
titanocene dibromide
;
X-ray analysis
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Molekular- und Kristallstruktur von Bis(η5-cyclopentadienyl)titan(IV)-dibromidDie Molecular- und Kristallstruktur von Bis(η5-cyclopentadienyl)titan(IV)-dibromid wurde durch Röntgenstrukturanalyse bestimmt. Kristalldaten: Triklin, Raumgruppe P1, a = 7,872(5), b = 11,807(5), c = 12,310(3) Å, α = 107,62(3), β = 100,83(4), γ = 90,69(4)°, V = 1 068(14) Å3, T = 293, Z = 4 (mit zwei kristallographisch unabhängigen Molekülen in der Elementarzelle und ähnlicher Konformation). Abschließende R-Werte: R = 0,068 und Rw = 0,073. Die Strukturergebnisse werden mit denen analoger Verbindungen verglichen.
Notes:
The crystal and molecular structure of Bis(η5-cyclopentadienyl)titanium(IV) dibromide, Ti(η5-C5H5)2Br2, has been investigated by an X-ray structure determination. Crystal data: triclinic, a = 7.872(5), b = 11.807(5), c = 12.310(3) Å, α = 107.62(3), β = 100.83(4), γ = 90.69(4)°, V = 1 068(14) Å3, T = 293, space group P1, Z = 4 (there are two crystallographically independent molecules in the asymmetric unit cell and their conformations are similar). Final R and Rw values are 0.068 and 0.073, respectively. The structural results are compared to those for similar type molecules.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936191117
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