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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 3065-3077 
    ISSN: 0887-6266
    Keywords: polyurethanes ; AFM ; atomic force microscopy ; phase separation ; crosslinking ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A series of polyurea urethanes was isothermally synthesized from toluene diisocyanate (TDI), water, and trifunctional poly(propylene oxide) in the temperature range of 50-150°C. Morphologies of the samples vary significantly as a function of reaction temperature. In this system, phase separation competes with polymerization and crosslinking. Both transmission electron microscopy and atomic force microscopy have shown a network type of structure for the 50°C samples, while the 150°C samples appear to be homogeneous. Infrared analysis shows that samples prepared at 150°C possess a morphology that is less strongly hydrogen bonded and has a broader distribution of hydrogen-bonded states compared to those prepared at lower temperatures. From this combination of techniques, it can be inferred that phase separation occurs faster than crosslinking at low temperatures; consequently, a phase-separated morphology forms. In contrast, crosslinking occurs faster than phase separation at higher reaction temperatures. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 3065-3077, 1998
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1097-1113 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: After flowing in a dilatometer bulb for a small fraction of the duration of the transformation, a relaxed melt of poly(ethylene oxide) (M̄n = (5.9 ± 0.1) × 103) showed marked increases in isothermal crystallization rate. The extent of increase was greater when flow was imposed at modestly later stages rather than at the earliest stage of a crystallization. Kinetic parameters for the flow-induced crystallizations were obtained via modification of the conventional mathematical treatment of the kinetics of phase change, thereby allowing the analytical resolution of the overall process into flowinduced and quiescent components. Determination of the flow-induced crystallization parameters required independent determination of the kinetic parameters for quiescent crystallizations at that temperature. The Avrami exponents nf which characterized the flow-induced portions of the crystallizations were larger for those instances in which flow was imposed at the more advanced stages of the crystallizations, thus indicating a transition in crystallization mechanism. It is suggested that prior crystallinity present at the time of flow contributed to the crystallization by serving as a source of nucleation sites. However, in light of the experimental procedure employed, values of nf approximating 4 that were obtained are not susceptible to mechanistic interpretations now extant.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 2679-2681 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 633-634 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 17 (1979), S. 497-513 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Solutions of cellulose (degree of polymerization: 296 ± 16) in tris(ethylenediamine)cadmium(II)hydroxide-ethylenediamine-water (cadoxen), 1.015% (weight per volume) were diluted 1:1.5 with water. The ensuing isothermal precipitations were followed dilatometrically at temperatures ranging from 27.50 to 48.45°C. The precipitation data were characterized by a positive temperature coefficient. They generally conformed to a one-dimensional nucleation rate law; the Avrami exponents were close to unity. Alternatively, they fit a first-order reaction rate expression with respect to cellulose concentration. The low crystallinity of the precipitated cellulose leads to the interpretation of the kinetics in terms of the dissociation of a cellulose-cadoxen complex, rather than phase separation, as the rate-determining step. The nucleation rate law suggests a one-dimensional nonrandom cooperative chemical process, while the first-order rate law suggests a random process.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 2651-2661 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A quasi-equilibrium model of a step-growth copolymer that crystallizes and interchanges structural units simultaneously is presented. Equilibrium values of counit-sequence-length distribution in the amorphous phase and degree of crystallinity are calculated in a system for which crystallite thickness is determined by nucleation. When applied to calculations, the model predicts that the counits of the amorphous phase will tend to be ordered in blocks. The crystalline content of the whole polymer and the extent of ordering counits along the chain decreases with increasing temperature. The model predicts temperature ranges for some whole copolymers in which one of two similarly stable, disparate combinations of crystallinity and sequence-length distribution may prevail.
    Additional Material: 9 Ill.
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  • 7
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    In:  http://aquaticcommons.org/id/eprint/15215 | 403 | 2014-06-01 19:03:11 | 15215 | United States National Marine Fisheries Service
    Publication Date: 2021-07-04
    Description: Status of the southeastern U.S. stock of red porgy (Pagrus pagrus) was estimated from fishery-dependent and fishery-independent data, 1972–97. Annual population numbers and fishing mortality rates at age were estimated from virtual population analysis (VPA) calibrated with fishery-independent data. For the VPA, a primary matrix of catch at age was based on age-length keys from fishery-independent samples; an alternate matrix was based on fishery-dependent keys. Additional estimates of stock status were obtained from a surplus-production model, also calibrated with fishery-independent indices of abundance.Results describe a dramatic increase in exploitation of this stock and concomitant decline in abundance. Estimated fully recruited fishing mortality rate (F) from the primary catch matrix increased from 0.10/yr in 1975 to 0.88/yr in 1997, and estimated static spawning potential ratio (SPR) declined from about 67% to about 18%. Estimated recruitment to age 1 declined from a peak of 3.0 million fish in 1973–74 to 94,000 fish in 1997, a decline of 96.9%. Estimated spawning-stock biomass declined from a peak of 3530 t in 1979 to 397 t in 1997, a decline of 88.8%. Results from the alternate catch matrix were similar. Retrospective patterns in the VPA suggest that the future estimates of this population decline will be severe, but may be less than present estimates.Long-term and marked declines in recruitment, spawning stock, and catch per unit of effort (both fishery-derived and fishery-independent)are consistent with severe overexploitation during a period of reduced recruitment. Although F prior to 1995 has generally been estimated at or below the current management criterion for overfishing (F equivalent to SPR=35%), the recent spawning-stock biomass is well below the biomass that could support maximum sustainable yield. Significant reductions in fishing mortality will be needed for rebuilding the southeastern U.S. stock.
    Keywords: Biology ; Ecology ; Fisheries ; Management
    Repository Name: AquaDocs
    Type: article , TRUE
    Format: application/pdf
    Format: application/pdf
    Format: 351-375
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  • 8
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    NOAA/National Centers for Coastal Ocean Science | Charleston, SC
    In:  http://aquaticcommons.org/id/eprint/14698 | 403 | 2014-02-25 19:51:22 | 14698 | United States National Ocean Service
    Publication Date: 2021-07-02
    Description: A study was initiated with field work in May 2007 to assess the status of ecological condition and stressor impacts throughout the U.S. continental shelf off South Florida, focusing on soft-bottom habitats, and to provide this information as a baseline for evaluating future changes due to natural or human-induced disturbances. The boundaries of the study region extended from Anclote Key on the western coast of Florida to West Palm Beach on the eastern coast of Florida, inclusive of the Florida Keys National Marine Sanctuary (FKNMS), and from navigable depths along the shoreline seaward to the shelf break (~100m). The study incorporated standard methods and indicators applied in previous national coastal monitoring programs — U.S. Environmental Protection Agency’s (EPA) Environmental Monitoring and Assessment Program (EMAP) and National Coastal Assessment (NCA) — including multiple measures of water quality, sediment quality, and biological condition. Synoptic sampling of the various indicators provided an integrative weight-of-evidence approach to assessing condition at each station and a basis for examining potential associations between presence of stressors and biological responses. A probabilistic sampling design, which included 50 stations distributed randomly throughout the region, was used to provide a basis for estimating the spatial extent of condition relative to the various measured indicators and corresponding assessment endpoints (where available). The study was conducted through a large cooperative effort by National Oceanic and Atmospheric Administration (NOAA)/National Centers for Coastal Ocean Science (NCCOS), EPA, U.S. Geological Survey (USGS), NOAA/Oceanic and Atmospheric Research (OAR)/Atlantic Oceanographic and Meteorological Laboratory in Miami, FKNMS, and the Florida Fish and Wildlife Conservation Commission (FWC).The majority of the South Florida shelf had high levels of dissolved oxygen (DO) in near-bottom water (〉 5 mg L-1) indicative of “good” water quality.. DO levels in bottom waters exceeded this upper threshold at 98.8% throughout the coastal-ocean survey area. Only 1.2% of the region had moderate DO levels (2-5 mg/L) and no part of the survey area had DO 〈2.0 mg/L. In addition, offshore waters throughout the region had relatively low levels of total suspended solids (TSS), nutrients, and chlorophyll a indicative of oligotrophic conditions.Results suggested good sediment quality as well. Sediments throughout the region, which ranged from sands to intermediate muddy sands, had low levels of total organic carbon (TOC) below bioeffect guidelines for benthic organisms. Chemical contaminants in sediments were also mostly at low, background levels. For example, none of the stations had chemicals in excess of corresponding Effects-Range Median (ERM) probable bioeffect values or more than one chemical in excess of lower-threshold Effects-Range Low (ERL) values. Cadmium was the only chemical that occurred at moderate concentrations between corresponding ERL and ERM values.Sixty fish samples from 28 stations were collected and analyzed for chemical contaminants. Eleven of these samples (39% of sites) had moderate levels of contaminants, between lower and upper non-cancer human-health thresholds, and ten (36% of sites) had high levels of contaminants above the upper threshold.
    Keywords: Ecology ; Fisheries ; Management
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
    Format: application/pdf
    Format: 68
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  • 9
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    NOAA/National Centers for Coastal Ocean Science | Charleston, SC
    In:  http://aquaticcommons.org/id/eprint/14762 | 403 | 2014-02-26 21:14:38 | 14762 | United States National Ocean Service
    Publication Date: 2021-07-03
    Description: In June 2008, the NOAA National Ocean Service (NOS), in conjunction with the EPA National Health and Environmental Effects Laboratory (NHEERL), conducted an assessment of the status of ecological condition of soft-bottom habitat and overlying waters within the boundaries of Stellwagen Bank National Marine Sanctuary (SBNMS). The sanctuary lies approximately 20 nautical miles east of Boston, MA in the southwest Gulf of Maine between Cape Ann and Cape Cod and encompassing 638 square nautical miles (2,181 km2). A total of 30 stations were targeted for sampling using standard methods and indicators applied in prior NOAA coastalstudies and EPA’s Environmental Monitoring and Assessment Program (EMAP) and National Coastal Assessment (NCA). A key feature adopted from these studies was the incorporation of a random probabilistic sampling design. Such a design provides a basis for making unbiased statistical estimates of the spatial extent of ecological condition relative to various measured indicators and corresponding thresholds of concern. Indicators included multiple measures of water quality, sediment quality, and biological condition (benthic fauna, fish tissue contaminant levels).Depths ranged from 31 – 137 m throughout the study area. About 76 % of the area had sediments composed of sands (〈 20 % silt-clay), 17 % of the area was composed of intermediate muddy sands (20 – 80 % silt-clay), and 7 % of the sampled area consisted of mud (〉 80 % siltclay). About 70 % of the area (represented by 21 sites) had sediment total organic carbon (TOC) concentrations 〈 5 mg/g and all but one site (located in Stellwagen Basin) had levels of TOC 〈 20 mg/g, which is well below the range potentially harmful to benthic fauna (〉 50 mg/g).Surface salinities ranged from 30.6 – 31.5 psu, with the majority of the study region (approximately 80 % of the area) having surface salinities between 30.8 and 31.4 psu. Bottom salinities varied between 32.1 and 32.5 psu, with bottom salinities at all sites having values above the range of surface salinities. Surface-water temperatures varied between 12.1 and 16.8 ºC, while near-bottom waters ranged in temperature from 4.4 – 6.2 ºC. An index of densitystratification (Δσt) indicated that the waters of SBNMS were stratified at the time of sampling. Values of Δσt at 29 of the 30 sites sampled in this study (96.7 % of the study area) varied from 2.1 – 3.2, which is within the range considered to be indicative of strong vertical stratification (Δσt 〉 2) and typical of the western Gulf of Maine in summer.Levels of dissolved oxygen (DO) were confined to a fairly narrow range in surface (8.8 – 10.4 mg/L) and bottom (8.5 – 9.6 mg/L) waters throughout the survey area. These levels are within the range considered indicative of good water quality (〉 5 mg/L) with respect to DO. None of these waters had DO at low levels (〈 2 mg/L) potentially harmful to benthic fauna and fish.
    Keywords: Conservation ; Ecology ; Fisheries ; Management
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
    Format: application/pdf
    Format: 59
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  • 10
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    In:  mike.prager@noaa.gov | http://aquaticcommons.org/id/eprint/14797 | 403 | 2014-02-28 19:21:41 | 14797 | United States National Marine Fisheries Service
    Publication Date: 2021-06-25
    Description: The recently revised Magnuson–Stevens Fishery Conservation and Management Act requires that U.S. fishery management councils avoid overfishing by setting annual catch limits (ACLs) not exceeding recommendations of the councils’ scientific advisers. To meet that requirement, the scientific advisers will need to know the overfishing limit (OFL) estimated in each stock assessment, with OFL being thecatch available from applying the limit fishing mortality rate to current or projected stock biomass. The advisers then will derive ‘‘acceptable biological catch’’ (ABC) from OFL by reducing OFL to allow for scientific uncertainty, and ABC becomes their recommendation to the council. We suggest methodology based on simple probability theory by which scientific advisers can compute ABC from OFL and thestatistical distribution of OFL as estimated by a stock assessment. Our method includes approximations to the distribution of OFL if it is not known from the assessment; however, we find it preferable to have the assessment model estimate the distribution of OFL directly. Probability-based methods such as this one provide well-defined approaches to setting ABC and may be helpful to scientific advisers as they translate the new legal requirement into concrete advice.
    Keywords: Fisheries ; Management
    Repository Name: AquaDocs
    Type: article , TRUE
    Format: application/pdf
    Format: application/pdf
    Format: 289-294
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