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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 35 (1997), S. 1087-1093 
    ISSN: 0887-624X
    Keywords: 8-acryloyloxyquinoline ; poly(8-acryloyloxyquinoline) ; fluorescence ; polymerizable photosensitizer ; structural self-quenching effect ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acrylic monomers bearing electron-donating quinolyl moiety, i.e., 8-acryloyloxyquinoline (AQ) was prepared and polymerized. It was found that the fluorescence intensity of AQ was much lower than that of P(AQ) at the same chromophore concentration. The fluorescence of P(AQ) could be quenched by electron-deficient vinyl monomers, such as acrylonitrile (AN) and methyl methacrylate (MMA). This is another example of the “fluorescence structural self-quenching effect” termed by us previously, and demonstrates again that this phenomenon is not an accidental but a general one for acrylic monomers bearing electron-donating chromophores. The photopolymerization of acrylonitrile (AN) sensitized by AQ and P(AQ) as well as combining with carbon tetrabromide (CBr4) was studied kinetically. From the rates of the polymerization (Rp) and overall activation energies obtained for these four systems, it was found that Rp sensitized by the binary systems was much higher than by AQ or P(AQ) alone, while the molecular weights of the resulting P(AN) were lower. The fluorescent analysis of the resulting P(AN) in solution showed that the sensitizers also entered into the P(AN) chains. A mechanism of charge transfer complex (CTC) formation was tentatively suggested for the photopolymerization of AN initiated by these four systems. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 1087-1093, 1997
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 9 (1997), S. 887-891 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 4 (1993), S. 8-11 
    ISSN: 1042-7147
    Keywords: Hemoglobin ; Vesicles ; Oxygen affinity ; Allosteric effectors ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The oxygen-carrying capacity of artificial red cells (ARC), which were prepared by encapsulating hemoglobin (Hb) into polymerized lipid vesicles, has been investigated in detail. It was found that the effects of inositol hexaphosphate (IHP) on the oxygen affinity of stromafree Hb and ARC are quite different. By co-encapsulating IHP at a IHP:Hb molar ratio of 1.0, the oxygen affinity of the encapsulated Hb in ARC was decreased to such an extent that P50 was about 60-65 mmHg, and only about 70-80% of the encapsulated Hb could be oxygenated at an oxygen partial pressure (Po2) of about 100 mmHg. As pyridoxal 5-phosphate (PLP) and chloride ions were coencapsulated instead of IHP, P50 and the Hill coefficient of the obtained ARC were adjusted to 25-30 mmHg and 2.5-2.8 respectively. The oxygen-transporting efficiency of PLP-modulated ARC was similar to or better than that of red blood cells.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 3 (1992), S. 17-21 
    ISSN: 1042-7147
    Keywords: Hemoglobin ; Vesicles ; Polymerized lipids ; Saccharides ; Freeze-drying ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The carbonyl hemoglobin (CO-Hb), which was used to prevent denaturation (metHb) during the preparation of samples, was encapsulated into lipid vesicles constituted from unsaturated phospholipid, cholesterol and unsaturated fatty acid. Unsaturated components were polymerized by γ-irradiation to enhance the stability of bilayer membrane. An aqueous dispersion of resulting Hb vesicles was freeze-dried in the presence of saccharides (50-200 mM) to obtain a dehydrated powder of Hb vesicles. Change in the vesicle size, the leakage of encapsulated Hb and the oxidation of Hb to metHb were not observed. Therefore, the long-term storage of Hb vesicles can be realized as a dry powder.
    Additional Material: 4 Ill.
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  • 5
    Publication Date: 2014-01-22
    Description: Author(s): Yutian Wang, Lin Li, Slawomir Prucnal, Xuliang Chen, Wei Tong, Zhaorong Yang, Frans Munnik, Kay Potzger, Wolfgang Skorupa, Sibylle Gemming, Manfred Helm, and Shengqiang Zhou We present a detailed investigation of the magnetic properties in SiC single crystals bombarded with neon ions. Through careful measuring of the magnetization of virgin and irradiated SiC, we decompose the magnetization of SiC into paramagnetic, superparamagnetic, and ferromagnetic contributions. Th... [Phys. Rev. B 89, 014417] Published Tue Jan 21, 2014
    Keywords: Magnetism
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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