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A Novel Infinite 1-D Chain of Silver(I) Bridged by trans-Azobenzene (2000)

Avilés, Teresa ; Dinis, António ; Drew, Michael G. B. ; [et al.]

Springer

Monatshefte für Chemie 131 (2000), S. 1305-1310

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ISSN: 1434-4475

Keywords: Keywords. Silver(I); Coordination polymer; trans-Azobenzene; Crystal structure.

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary. The self-assembly of Ag[BF4] with trans-azobenzene in dichloromethane yields a new coordination polymer ([Ag(μ-trans-azobenzene)H2O][BF4])n which was characterized by X-ray single crystal diffraction. The crystal consists of 1-D zigzag cationic chains made up from [Ag(H2O)]+ units linked by trans-azobenzene bridges and BF− 4 anions. Hydrogen bonding interactions between the chains and BF− 4 anions occur via intermolecular C*H⋯F and O*H⋯F contacts, and the crystal displays a 2-D supramolecular structure.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/s007060070009

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