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  • 1
    ISSN: 1435-1536
    Keywords: Key words Non-linear optics ; electron diffraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  4-Dimethylamino-3-cyanobiphenyl (4-DMA-3-CB) was characterized with respect to linear and nonlinear optical properties in a crystal as well as in solution. The crystal structure was studied dependent on the crystallization conditions. It is shown that the crystal structure exhibiting NLO-activity can completely be solved by a combination of electron diffraction and computer modeling. There are four molecules per unit cell in the space group Pna21 with dimensions a=10.28 Å, b=22.64 Å, c=5.27 Å. From this model structure the values and orientation of the dipole μ and static second order polarizability β can be calculated. Their relevance to the values obtained by a combination of polarization dependent measurements of Electric Field Induced Second Harmonic Generation (EFISH) and Hyper-Rayleigh-Scattering (HRS) in solution are discussed. The molecular second order polarizability tensor was found to be dominated by one single component. The orientations of the dipole and the vectorial parts of the second order polarizability delivered by the semiempirical calculations are in good agreement with the results of the EFISH and HRS-measurements and allow a deeper insight into the nonlinear optical properties of the crystal.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2018-09-27
    Description: Author(s): Liang Wu, A. Little, E. E. Aldape, D. Rees, E. Thewalt, P. Lampen-Kelley, A. Banerjee, C. A. Bridges, J.-Q. Yan, D. Boone, S. Patankar, D. Goldhaber-Gordon, D. Mandrus, S. E. Nagler, E. Altman, and J. Orenstein The quantum spin liquid (QSL) – a phase of matter with no ordered ground state – is of fundamental interest as excitations in this phase may break the molds of bosons and fermions and develop more complicated properties. The honeycomb magnet α -RuCl 3 has emerged as a candidate for realization of a QSL. Although it orders at low temperature, an in-plane magnetic field of around 7 Tesla destroys the order; the nature of this transition is intensely studied. Here, the authors use polarized time-domain terahertz spectroscopy to study the spectrum of magnetic excitations in α -RuCl 3 in an applied field. Motivated by the unusual evolution of the spectra, the authors develop a linear spin wave theory to describe the data with strikingly good agreement. These results provide clarity for ongoing work on this compound, and inform future studies aiming to detect field-induced QSL states. [Phys. Rev. B 98, 094425] Published Wed Sep 26, 2018
    Keywords: Magnetism
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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