ISSN:
0009-2940
Keywords:
Niobium complexes
;
Tantalum complexes
;
Siloxy group
;
Silylamide
;
Silylimide
;
NMR, 17O
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Multiple Bonds Between Main-Group Elements and Transition Metals, XCVI. - Niobium and Tantalum Complexes Having Imido LigandsThe new niobium and tantalum complexes 2b and 2c of formula M[N(SiMe3)2]2(NSiMe3)(OSiMe3) (M = Nb, b; Ta, c) are accessible by the reaction of the oxychlorides MOCl3 with the lithium amide LiN[Si(CH3)3]2 in 36 and 27% isolated yield, respectively.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241104
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