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  • 1
    facet.materialart.
    Unbekannt
    In:  CASI
    Publikationsdatum: 2013-08-31
    Beschreibung: The goal of this study was threefold. First, the theoretical energy requirements of the process were to be defined. This includes studies of the relevant oxidation-reduction reactions in the melt, their kinetics and energies of reaction, and experimental determination of production efficiencies and melt resistivities as functions of melt composition and applied potential. Second, the product(s) of silicate electrolysis were to be characterized. This includes: (1) evaluating the phase relationships in the systems SiO2-TiO2-Al2O3-MgO-FeO-CaO and Fe-Si; (2) estimating the compositions of the metal products as a function of applied potential and feedstock composition based on phase equilibria in the Fe-Si system and free energy values for SiO2 and FeO reported in the literature; (3) definition of compositions of products in actual experiments; and (4) definition of the form the product takes (whether phases separate or remain fixed, whether crystals settle or float in the remaining melt, and how large crystals form). Third, materials for these highly corrosive high-temperature silicate melts were to be identified. This includes identifing materials that may be either inert or thermodynamically stable in these melts, and experimental testing of the materials to confirm that they do not deteriorate. The results are discussed within this framework.
    Schlagwort(e): INORGANIC AND PHYSICAL CHEMISTRY
    Materialart: Arizona Univ., NASA Space Engineering Research Center for Utilization of Local Planetary Resources; 10 p
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    facet.materialart.
    Unbekannt
    In:  CASI
    Publikationsdatum: 2013-08-31
    Beschreibung: Previous work has shown that Fe(sup 0) and O2 can be derived by electrolysis from silicate smelt of a composition typical of lunar soils (Lindstrom and Haskin 1979). In the present study, the goal is to refine further the conditions necessary to optimize production and to determine efficiencies of production (how much product is derived for a given current) and purity of products. These depend on several factors, including potential imposed between electrodes, configuration and surface area of the electrodes, composition of the electrolyzed silicate melt, and oxygen fugacity. Experiments were designed to measure the dependence on these variables of three parameters that must be known before production by electrolysis can be optimized. These parameters are: Limiting Current; Actual Current; and Efficiencies of Production.
    Schlagwort(e): INORGANIC AND PHYSICAL CHEMISTRY
    Materialart: Arizona Univ., NASA Space Engineering Research Center for Utilization of Local Planetary Resources; 6 p
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2019-08-28
    Beschreibung: Parameters are estimated for a hypothetical, well stirred, continuous-feed electrolytic cell that converts 20 percent of a lunar soil feedstock to O2 gas, 26 percent to Fe-Si metal, 13 percent to spinel, and 41 percent to slag. Advantages of a molten Fe-Si cathode for trapping metal on reduction, a relatively conductive steady-state composition in equilibrium with spinel (a proposed container material), and close electrodes (less than 1 cm cathode-anode distance) are discussed. To produce 1 ton of O2, about 6 MHW of energy are required for the electrolysis and IR heating within the melt, and another about 6 MHW may be introduced as waste heat through internal resistance of the electrodes. Thus, to produce 1 ton of O2 per 24 hours, about 0.5 MW of power delivered to the cell would be required.
    Schlagwort(e): INORGANIC AND PHYSICAL CHEMISTRY
    Materialart: In: Engineering, construction, and operations in space - III: Space '92; Proceedings of the 3rd International Conference, Denver, CO, May 31-June 4, 1992. Vol. 1 (A93-41976 17-12); p. 651-665.
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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