ISSN:
0009-2940
Keywords:
Transition-metal chemistry
;
Hydrogen exchange
;
Gas-phase oxidation
;
Fourier-transform ion-cyclotrone resonance
;
Tandem mass spectrometry
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Gas-phase experiments on the Fe+-mediated oxidation of 2-propanol and ethanol by 1,3-butadiene are described. The reaction takes place at an atomic Fe+ centre, and labeling experiments uncover its specificity. While the gas-phase reaction of Fe(η4-C4H6)+ with 2-propanol occurs at collision-rate and the analysis of ligand-binding energies, in principle, favour a catalytic cycle for the Fe+-mediated dehydrogenation of 2-propanol by 1,3-butadiene, this conjecture is not born out experimentally due to complicating “side” processes. In addition to the specific interligand two-hydrogen-atom transfer from the alcohol to butadiene, the study of isotopomers reveals several hydrogen-exchange processes preceding dehydrogenation, dehydration, and alkene loss from (C4H6)Fe+ (alcohol) complexes.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250331
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