ISSN:
0947-3440
Keywords:
Organic donor
;
Tetrathiatetralin
;
Tetrathiafulvalene
;
Solvent effects
;
Heterocycles
;
Sulfur
;
Selenium
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Tetrakis(methylthio)- and tetrakis(methylseleno)-1,4,5,8-tetrathiatetralin 3 and 4 were prepared by the reaction of tetrathiatetralin 2 with LDA (lithium diisopropylamide) and MeS-SMe or MeSeSeMe in diethyl ether. A remarkable solvent effect was observed in that the similar reaction in tetrahydrofuran gave tetrakis(methylthio)tetrathiafulvalene 5 through a novel rearrangement. The iodine complex of 3 was prepared to be a rare example of complex formation in the tetrathiatetralin series.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970414
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