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  • 11
    Publication Date: 2019-07-13
    Description: The assessment of indigenous organic matter in returned lunar samples was one of the primary scientific goals of the Apollo program. The levels of such organic material were expected to be and found to be small. Previous work on this topic includes Murphy et al. [1] who reported the presence of anthropogenic organics with sub-ppm concentrations in Apollo 11 fines. In Apollo 12 samples, Preti et al. [2] detected low levels, 〈 10 ppb or below, of more complex organic material that may have been synthesized by abrupt heating during analysis. Kvenvolden et al. [3] detected porphyrin-like pigments at the ng to pg level in an Apollo 11 bulk sample. Hodgson et al. [4] and Ponnamperuma et al. [5] suggested that most if not all porphyrins were synthesized from rocket fuel during module landing. Chang et al. [6] reported indigenous carbon ranging from 5-20 g/g in the form of metal carbides in Apollo 11 fines. Hare et al. [7] reported amino acids at he 50 ng/g level in Apollo 11 samples but suggested the results may be explained as contamination. More recently, Clemett et al. [8] reported simple polycyclic aromatic hydrocarbons at concentrations of 〈 1ppm in an Apollo 16 soil. Low concentrations of lunar organics may be a consequence not only of its paucity, but also its heterogeneous distribution. If the sample size required for a measurement is large relative to the localization of organics, detection is limited not by ultimate sensitivity but rather by the ability to distinguish an indigenous signature from background contamination [9].
    Keywords: Geophysics
    Type: JSC-CN-25667 , 43rd Lunar aud Plauetary Science Conference; Mar 19, 2012 - Mar 23, 2012; The Woodlands, TX; United States
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  • 12
    Publication Date: 2019-07-13
    Description: Recently acquired microwave data obtained from the NASA CV 990 research aircraft have yielded variation of sea surface emissivity as a function of various parameters. Data acquired at a wavelength of 1.5 cm, horizontal polarization, agree with data obtained earlier by Nordberg et al. and Hollinger at nadir and 50 deg viewing angles respectively; the ratio of brightness temperature change to wind speed change was found to be approximately 1 K per meter per second over a wind speed range of 5 to 26 meters per second. Combining these recent measurements with the earlier measurements, it is evident that microwave radiometry can be used as a remote-sensing anemometer over all wind speed ranges of interest. Data analysis revealed that for nadir-viewing instruments, the ratio of brightness temperature change to wind speed change was approximately constant for the 0.8-2.8 cm wavelength range, about three-quarters of that value at 6 cm, and nearly zero at 21 cm. A model is proposed that is consistent with observations.
    Keywords: OCEANOGRAPHY
    Type: Specialist Meeting on Microwave Scattering and Emission from the Earth; Sep 23, 1974 - Sep 26, 1974; Berne; Switzerland
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  • 13
    Publication Date: 2019-07-13
    Description: The application of synthetic aperture microwave radar imagery to the measurement of ocean wave direction and wavelength is discussed and an airborne experiment conducted in preparation for the SEASAT-A satellite mission is presented. Models for radar backscattering are examined and it is concluded that the Bragg-Rice model, which represents the ocean surface as a combination of periodic surfaces so that the dominant backscatter matches some portion of the wave spectrum, appears most useful. The experiment was conducted with airborne X-band and L-band synthetic aperture radar (SAR) and data was compared with that obtained from a pitch-and-roll buoy and an instrument package mounted on a sea sled. SAR data was converted to wave spectra and it was found to match data from the buoy, while SAR data on wave direction agrees to within two degrees with the buoy and to within one degree with the sea sled sensors. Wave direction data taken by two real aperture radars is also presented and shown to agree with airborne photographs.
    Keywords: OCEANOGRAPHY
    Type: Oceans ''78: The ocean challenge; Fourth Annual Combined Conference; Sep 06, 1978 - Sep 08, 1978; Washington, DC
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  • 14
    Publication Date: 2019-07-20
    Description: Since its development by Wark and Watson (2006), the Ti-in-quartz geothermometer (TitaniQ) has been continuously refined and applied to a variety of lithologies from different crustal settings. Assuming quartz crystallized and incorporated Ti under equilibrium conditions and providing TiO2 activity (alpha (sub TiO2)) is reasonably constrained, crystallization temperatures at typical crustal pressures can be calculated. In turn, when crystallization temperatures are independently constrained, Ti-in-quartz can be used as a geobarometer. Here we explore the application of this technique to impact lithologies. Quartz is ubiquitous in terrestrial impact structures in upper crustal settings and can also form as a post-impact hydrothermal mineral. Together with other geothermometers, such as Ti-in-zircon, Ti-in-quartz can potentially help constrain the temperature-pressure conditions during the formation of the pre-impact target rock at terrestrial impact structures, as well as impact-produced and hydrothermally-altered lithologies. This work presents the first systematic Ti-in-quartz study of impactites and granitoid target rocks from the approximately180-kilometer-diameter, end-Cretaceous Chicxulub crater on the Yucatan Peninsula, Mexico, thereby placing new constraints on the emplacement of felsic plutons within the Maya Block in the Paleozoic, impact melt crystallization at approximately 66 Ma (million years ago), and post-impact hydrothermal overprint inside the Chicxulub crater.
    Keywords: Geophysics
    Type: LPI Contrib. No. 2132 , JSC-E-DAA-TN65671 , Lunar and Planetary Science Conference (LPSC 2019); 18ý22 Mar. 2019; The Woodlands, TX; United States
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  • 15
    Publication Date: 2019-07-13
    Description: Recent remote sensing studies [e.g., 1-3] indicate that several un-sampled regions of the Moon have significantly higher concentrations of silicic material (also high in [K], [U], and [Th]) than sampled regions. Within these areas are morphological features that are best explained by the existence of chemically evolved volcanic rocks. Observations of silicic domes [e.g., 1-5] suggest that sizable networks of silicic melt were present during crust-formation. Because of these recent findings there is a renewed interest in the petrogenesis of lunar, felsic igneous rocks. Specific questions are: (1) when were these magmas generated?, and (2) what was the source material? The two main hypotheses for generating silicic melts on Earth are fractional crystallization or partial melting of preexisting crust. On the Moon silicic melts are thought to have been generated during extreme fractional crystallization involving end-stage silicate liquid immiscibility (SLI) [e.g. 6, 7]. However, SLI cannot account for the production of significant volumes of silicic melt and its wide distribution, as reported by the remote global surveys [1, 2, 3]. In addition, experimental and natural products of SLI show that U and Th, which are abundant in the lunar granites and seen in the remote sensing data of the domes, are preferentially partitioned into the depolymerized ferrobasaltic magma and not the silicic portion [8, 9]. If SLI is not the mechanism that generated silicic magmas on the Moon then alternative processes such as fractional crystallization (only crystal-liquid separation) or partial melting should be considered as viable possibilities to be tested.
    Keywords: Geophysics
    Type: JSC-CN-28074 , Lunar and Planetary Science Conference; Mar 18, 2013 - Mar 22, 2013; The Woodlands, TX; United States
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  • 16
    Publication Date: 2019-07-13
    Description: Immiscible sulfide melt spherules are locally very abundant in shergottite impact melts. These melts can also contain samples of Martian atmospheric gases [1], and cosmogenic nuclides [2] that are present in impact melt, but not in the host shergottite, indicating some components in the melt resided at the Martian surface. These observations show that some regolith components are, at least locally, present in the impact melts. This view also suggests that one source of the over-abundant sulfur in these impact melts could be sulfates that are major constituents of Martian regolith, and that the sulfates were reduced during shock heating to sulfide. An alternative view is that sulfide spherules in impact melts are produced solely by melting the crystalline sulfide minerals (dominantly pyrrhotite, Fe(1-x)S) that are present in shergottites [3]. In this abstract we report new analyses of the compositions of sulfide immiscible melt spherules and pyrrhotite in the shergottites Tissint, and EETA79001,507, and we use these data to investigate the possible origins of the immiscible sulfide melt spherules. In particular, we use the metal/S ratios determined in these blebs as potential diagnostic criteria for tracking the source material from which the numerous sulfide blebs were generated by shock in these melts.
    Keywords: Geophysics
    Type: JSC-CN-27989 , Lunar and Planetary Science Conference; Mar 18, 2013 - Mar 22, 2013; The Woodlands, TX; United States
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  • 17
    Publication Date: 2019-07-13
    Description: We have recently discovered the first well-preserved calcium aluminum-rich inclusion (CAI) in a CI1 chondrite (Ivuna). Previously, all CI1 chondrites were thought to be devoid of preserved CAI and chondrules due to the near total aqueous alteration to which their parent body (bodies) have been subjected. The CAI is roughly spherical, but with a slight teardrop geometry and a maximum diameter of 170 microns (fig. 1). It lacks any Wark-Lovering Rim. Incipient aqueous alteration, and probably shock, have rendered large portions of the CAI poorly crystalline. It is extremely fine-grained, with only a few grains exceeding 10 microns. We have performed electron microprobe analyses (EPMA), FEG-SEM imaging and element mapping, as well as electron back-scattered diffraction (EBSD) and synchrotron X-ray diffraction (SXRD) in order to determine the fundamental characteristics of this apparently unique object.
    Keywords: Geophysics
    Type: JSC-CN-22691 , 42nd Lunar and Planetary Science Conference; Mar 07, 2011 - Mar 11, 2011; The Woodlands, TX; United States
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  • 18
    Publication Date: 2019-07-13
    Description: Differentiated and partially differentiated asteroids preserve a glimpse of planet formation frozen in time from the early solar system and thus are attractive targets for future exploration. Samples of such asteroids arrive to Earth in the form of achondrite meteorites. Many achondrites, particularly those thought to be most representative of asteroidal regolith, contain a diverse assortment of materials both indigenous and exogenous to the original igneous parent body intermixed at microscopic scales. Remote sensing spacecraft and landers would have difficulty deciphering individual components at these spatial scales, potentially leading to confusing results. Sample return would thus be much more informative than a robotic probe. In this and a companion abstract [1] we consider two regolithic achondrite types, howardites and (polymict) ureilites, in order to evaluate what materials might occur in samples returned from surfaces of differentiated asteroids and what sampling strategies might be prudent.
    Keywords: Geophysics
    Type: JSC-CN-22756 , 42nd Lunar and Planetary Science Conference; Mar 07, 2011 - Mar 11, 2011; The Woodlands, TX; United States
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