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  • 1
    Online Resource
    Online Resource
    Cham :Springer International Publishing :
    Keywords: Geochemistry. ; Geology. ; Thermodynamics. ; Geochemistry. ; Geology. ; Thermodynamics.
    Description / Table of Contents: Introduction -- Thermodynamics, geochemical modeling and related considerations -- The selected reservoir liquids -- The hydrothermal minerals -- The traditional water geothermometers and fCO2-indicators -- The activity-based theoretical Na-K geoindicators -- The activity-based theoretical K-Mg and Na-Mg geoindicators -- The activity-based theoretical K-Ca and Na-Ca geoindicators -- Conclusions and way forwards -- References.
    Abstract: This book explores water geothermometry, a highly relevant topic in the exploration and exploitation of geothermal energy. Presenting theoretical geothermometers and indicators of CO2 fugacity, it describes a rigorous new approach entirely based on thermodynamics. The book will appeal to geothermal geoscientists, especially those working in research institutions and companies around the globe. It is also of interest to students on advanced courses in applied geochemistry, water–rock interaction and other related areas.
    Type of Medium: Online Resource
    Pages: XV, 415 p. 168 illus., 160 illus. in color. , online resource.
    Edition: 1st ed. 2020.
    ISBN: 9783030543181
    Series Statement: Springer Geochemistry,
    DDC: 551.9
    Language: English
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  • 2
    Keywords: Geology. ; Geochemistry. ; Thermodynamics. ; Mineralogy. ; Geology. ; Geochemistry. ; Thermodynamics. ; Mineralogy.
    Description / Table of Contents: Preface -- Introduction -- 1. Historical data -- 2. Summary of the Campi Flegrei geology -- 3. The magmatic – hydrothermal system hosted in the Campi Flegrei caldera with emphasis on the Solfatara -- 4. The expansion (decompression) of the Solfatara fumarolic fluids -- 5. Chemical and isotopic characteristics of Solfatara-Pisciarelli fumarolic fluids -- 6. The geoindicators involving H2O, CO2, CO, CH4 and H2 -- 7. The chemical kinetics of the reactions involving H2O, CO2, CO, CH4 and H2 -- 8. Calibration and application of the RWG and SS4 indicators for the possible expansion paths of Solfatara fluids -- 9. The redox potential and sulfur gas species -- 10. Soil CO2 diffuse degassing and thermal energy release as indicators of volcanic unrest in the Solfatara-Pisciarelli area -- 11. A comparison between the Solfatara and other magmatic-hydrothermal systems -- 12. Conclusive remarks.
    Abstract: This book includes innovative gas-geothermometers and geobarometers, which are urgently needed to estimate the increasingly higher temperatures and pressures present at depth below the Solfatara volcano, owing to its on-going unrest. Therefore, in this book, new gas geoindicators, applicable up to ca. 1000°C and 3 kbar, have been implemented and applied to Solfatara fluids. The innovations of this book include: methane, having a sluggish behavior, was treated separately from fast-reacting carbon monoxide; deviations from the ideal gas behavior were considered; the effects of reaction kinetics were taken into account. This was possible because a dataset including many geochemical parameters and extending from 1983 to 2020 with a good sampling frequency is available for Solfatara, making it a case history probably unique worldwide. Nevertheless, the gas geoindicators described in this book can be applied to other similar systems. Thus, this book is of interest to many scientists studying gas geochemistry, geothermometry, and geobarometry for volcanic surveillance and the mitigation of the volcanic risk. .
    Type of Medium: Online Resource
    Pages: XVIII, 375 p. 191 illus., 175 illus. in color. , online resource.
    Edition: 1st ed. 2022.
    ISBN: 9783030984717
    Series Statement: Advances in Volcanology, An Official Book Series of the International Association of Volcanology and Chemistry of the Earth’s Interior,
    DDC: 551
    Language: English
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