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Untersuchungen zur Chlorokomplexbildung des Gallium(III)-kations in wäßriger Lösung (1992)

Brendler, Erica ; Thomas, Berthold ; Schönherr, Siegfried

Springer

Monatshefte für Chemie 123 (1992), S. 285-289

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ISSN: 1434-4475

Keywords: Gallium-chloro complexes ; 71Ga-NMR ; Raman spectroscopy

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary Using aqueous GaCl3 and chloride containing Ga(ClO4)3 solutions measurements have been carried out to investigate the formation of complexes with mixed ligands beside the [GaCl4]− ion. In contrast to the Raman spectra, which contain only the signals of the [GaCl 4 − ] and the [Ga(H2O)6]3+ ion, the71Ga-NMR spectra give clear evidence for the existence of complexes with mixed ligands. Investigations at low temperatures showed their coordination to be octahedral resulting in species [GaCln(H2O)6−n ](3−n)+.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00810938

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