ALBERT

Description: Nitrous oxide (N2O) measured on board the ER-2 aircraft during the Airborne Arctic Stratospheric Expedition 2 (AASE 2) has been used to monitor descent of air inside the Arctic vortex between October 1991 and March 1992. Monthly mean N2O fields are calculated from the flight data and then compared with mean fields calculated from the high-resolution Geophysical Fluid Dynamics Laboratory general circulation model SKYHI in order to evaluate the model's simulation of the polar vortex. From late fall through winter the model vortex evolves in much the same way as the 1991-1992 vortex, with N2O gradients at the edge becoming progressively steeper. The October to March trends in N2O profiles inside the vortex are used to verify daily net heating rates in the vortex that were computed from clear sky radiative heating rates and National Meteorological Center temperature observations. The computed heating rates successfully estimate the descent of vortex air from December through February but suggest that before December, air at high latitudes may not be isolated from the midlatitudes. SKYHI heating rates are in good agreement with the computed rates but tend to be slightly higher (i.e., less cooling) due to meteorological differences between SKYHI and the 1991-1992 winter. Three ER-2 flights measured N2O just north of the subtropical jet. These low-midlatitude profiles show only slight differences from the high-midlatitude profiles (45 deg - 60 deg N), indicating strong meridional mixing in the midlatitude 'surf zone.' Mean midwinter N2O profiles inside and outside the vortex calculated from AASE 2 data are shown to be nearly identical to 1989 AASE profiles, pointing to the N2O/potential temperature relationship as an excellent marker for vortex air.

Description: Vertical profiles of N2O and NO(y) taken by the ER-2 outside the vortex are used to construct average vertical profiles of F(NO(y)) = NO(y)/(A-N2O), where A is the tropospheric content of N2O three years prior to the measurements. The southern hemisphere had less nitrous oxide in the range 400 less than Theta less than 470 K, by up to 25% relative to the northern hemisphere. F(NO(y)) is the ratio of NOy produced to N2O lost in a stratospheric air mass since entry from the troposphere. The profiles of F(NO(y)) have the following characteristics: (1) Relative to 1991-1992, a year without denitrification inside or outside the vortex, the northern hemisphere in 1988-1989 showed denitrification outside the vortex ranging up to 25% and averaging 17% above Theta = 425 K. (2) Relative to the northern hemisphere in 1991-1992, the southern hemisphere in 1987 showed denitrification outside the vortex ranging up to 32% and averaging 20% above Theta = 400 K. (3) Below Theta = 400 K the southern hemisphere showed enhancements of F(NO(y)) relative to the northern hemisphere in 1991-1992 ranging up to 200% at Theta = 375 K, outside the vortex. Corresponding profiles of residual water, R(H2O) = H2O - 2(1.6 - CH4), are considered and shown to be consistent with those of F(NO(y)) in the sense that they show deficits outside the Antarctic vortex, which was both dehydrated and denitrified, but not outside the 1988-1989 Arctic vortex, which was denitrified but not dehydrated. R(H2O) is the water content of stratospheric air with the contribution from methane oxidation subtracted. Comparison of F(NO(y)) and R(H2O) below 400 K outside the Antarctic vortex leads to the suggetion that dehydration in the Antarctic vortex occurs by the sedimentation of ice crystals large enough to fall out of the stratosphere, whereas denitrification occurs mainly on mixed nitric acid-water crystals which evaporate below the base of the vortex at Theta = 400 K but above the tropopause.

Description: The paper uses particle size and volume measurements obtained with the forward scattering spectrometer probe model 300 during January and February 1989 in the Airborne Arctic Stratospheric Experiment to investigate processes important in the formation and growth of polar stratospheric cloud (PSC) particles. It is suggested on the basis of comparisons of the observations with expected sulfuric acid droplet deliquescence that in the Arctic a major fraction of the sulfuric acid droplets remain liquid until temperatures at least as low as 193 K. It is proposed that homogeneous freezing of the sulfuric acid droplets might occur near 190 K and might play a role in the formation of PSCs.

Description: The pairwise correlation of NO(y) and N2O data from the Southern and Northern Hemispheres is presented. Both data sets show a linear correlation region, defined as a reference state, and regions of denitrification where the correlation breaks down. Using two-dimensional photochemical model simulations of the atmosphere, a similar linear correlation is found between NO(y) and N2O, thereby establishing a theoretical framework for the reference state. This general approach, which can be extended to other pairs of molecules, should prove to be powerful in further comparisons of aircraft data with numerical models.

Description: Analysis of small-scale structure in the in situ measurements made from the ER-2 during the Airborne Antarctic Ozone Experiment shows the existence of a region at the boundary of the chemiclly perturbed region where the mixing ratios and small-scale structure of trace gases are influenced by transport across the boundary. This transition region is characterized by horizontal interchange and vertical layering of air parcels from within and outside of the chemically perturbed region and negative small-scale correlations between ClO and ozone. The horizontal transport in this region creates large surface areas between dissimilar air masses, providing the potential for substantial mixing. Correlations between ClO and O3 show that the transition region extends to 2-4 deg of latitude to either side of the boundary of the chemically perturbed region. A + or - 4-deg-wide transition region would contain nearly as much air as the chemically perturbed region proper. Analysis of water vapor and nitrous oxide data suggests that diabatic descent is associated with dehydration. This could be caused by strong radiative cooling of those polar stratospheric clouds in which enough water condenses for the particles to fall and dehydrate the air.

Description: Fluid dynamic aspects of the Antarctic ozone hole phenomena are studied. Data collected by the ER-2 aircraft as part of the Airborne Antarctic Ozone Experiment (AAOE) are used to calculate the potential vorticity distribution on potential temperature surfaces. Most of the ER-2 flights show a monotonic decrease in potential vorticity and nitrous oxide toward the pole on isentropic surfaces.

Description: In situ N2O measurements were made using an airborne tunable laser absorption spectrometer (ATLAS) on 12 flights into the Antarctic vortex, as well as on five transit flights outside the vortex region in August and September 1987, as part of the Airborne Antartic Ozone Experiment. Vertical profiles of N2O were obtained within the vortex on most of these flights and were obtained outside the vortex on several occasions. Flights into the vortex region show N2O decreasing southward between 53 and 72 S latitude on constant potential temperature surfaces in the lower stratosphere. The data lead to two important conclusions about the vortex region: (1) the lower stratosphere in August/September 1987 was occupied by 'old' air, which had subsided several kilometers during polar winter; (2) the N2O profile in the vortex was in an approximately steady state in August/September 1987, which indicates that the spring upwelling, suggested by several theories, did not occur.

Description: Composite distributions of measured total reactive nitrogen NO(y), from the NASA ER-2 during the Airborne Arctic Stratospheric Expedition are presented. The observed features of these distributions are discussed in terms of the controlling dynamical, chemical and microphysical processes. In the latitudinal profile from 58 deg N to within about 4 deg poleward of the polar vortex boundary, NO(y) conforms closely to predictions of NO(y) based on N2O measurements. Poleward of 5 deg of latitude within the boundary, the average NO(y) decreases sharply and is significantly lower than that predicted from N2O. This feature is consistent with loss of NO(y) through sedimentation of particles containing NO(y) in polar stratospheric clouds.

Description: In-situ particle measurements made aboard the NASA ER-2 in the Arctic on 890130 (YYMMDD) show Type 1 PSC particles over much of the flight, with instances of embedded Type 2 PSCs. The Type 2 particles were observed at temperatures warmer than the local frost-point temperature of water; extended up to the upper size cutoff of the instrument (about 24-micron diameter); and are shown to contain too large a volume to be primarily NAT. Based on measured vertical temperature profiles, it is concluded that the Type 2 particles observed on this day were formed above the aircraft in a region where saturation with respect to ice was achieved and were sufficiently large to have fallen into the path of the ER-2. Although the amount of material in the particles, expressed as water, is small by comparison to the total (vapor + aerosol) water concentration, the flux of water from the falling particles is of sufficient magnitude, if sustained, to lead to dehydration of the source region. These observations verify the mechanism for dehydration of polar vortex air masses by precipitation of ice particles.

Description: Large-scale distributions of ozone (O3) were measured with an airborne lidar system as part of the 1989 Airborne Arctic Stratospheric Expedition. Measurements of O3 distributions were obtained between January 6 and February 15, 1989, on 15 long-range flights into the polar vortex from the Solar Air Station, Norway. The observed O3 distribution was found to clearly indicate the edge of the polar vortex and to be an effective tracer of dynamical processes in the lower stratosphere. On the last two flights of the expedition, large regions with reduced O3 levels were observed by the lidar inside the polar vortex. Ozone had decreased by as much as 17 percent in the center of these areas, and using the in situ measurements made on the ER-2 aircraft, it was concluded that this decline was due to chemical O3 destruction.