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  • 1
    Publication Date: 2019-06-28
    Description: The densities and vibrational distributions of N2(+) in the X2sigma g +, A2Pi u and B2sigma u + states in the daytime terrestrial ionosphere are computed for both low and high solar activity. Altitude profiles of the relative populations of the vibrational levels of N2(+) X2sigma g + are presented. The fraction of vibrationally excited N2(+) varies from 5 percent at 100 km to 50 percent at 450 km. Several models are examined in which loss of N2(+)(v) is enhanced for v greater than 0 and in which various assumptions are made about the vibrational distributions produced in charge transfer reactions. The N2(+) densities are significantly reduced if N2(+)(v) reacts with O at rates which are near gas-kinetic. Vibrational distributions of the A2pi u and B2sigma u + states are also presented, as well as volume emission rates and integrated overhead intensities of the major bands of the Meinel and first negative systems.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 90; 7557-756
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  • 2
    Publication Date: 2019-06-28
    Description: The equations which determine partitioning of Cl(x) in steady state have multiple (three) solutions under conditions which might arise in the high-latitude winter stratosphere. Two of these solutions are stable, one is unstable, to infinitesimal perturbations. The relative stability of solutions is examined by subjecting the system to finite perturbations. The more stable solution is found to eliminate the less stable when semi-infinite volumes of the two solutions are placed in contact. The high-ClO, low NO2 solution is more stable under most conditions. Transitions from less to more stable states are slow in winter but may occur more rapidly when the seasonal variation of insolation is taken into account.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research; 87; Dec. 20
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  • 3
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    In:  Other Sources
    Publication Date: 2019-07-13
    Description: Evidence has been advanced that the rate coefficient for the reaction N + NO right arrow N2 + O has a small positive temperature dependence at the high temperatures (900 to 1500 K) that prevail in the terrestrial middle and upper thermosphere by Siskind and Rusch (1992), and at the low temperatures (100 to 200 K) of the Martian lower thermosphere by Fox (1993). Assuming that the rate coefficient recommended by the Jet Propulsion Laboratory evaluation (DeMore et al., 1992) is accurate at 300 K, we derive here the low temperature value of the activation energy for this reaction and thus the rate coefficient that best fits the Viking 1 measured NO densities. We find that the fit is acceptable for a rate coefficient of about 1.3 x 10(exp -10)(T/300)(exp 0.5)exp(-400/T) and better for a value of about 2.5 x 10(exp -10)(T/300)(exp 0.5)exp(-600/T)cu cm/s.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; A4; p. 6273-6276
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  • 4
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    In:  Other Sources
    Publication Date: 2019-08-27
    Description: Ionization in planetary atmospheres can be produced by solar photoionization, photoelectron impact ionization, and, in auroral regions, by impact of precipitating particles. This ionization is lost mainly in dissociative recombination (DR) of molecular ions. Although atomic ions cannot undergo DR, they can be transformed locally through ion-molecule reactions into molecular ions, or they may be transported vertically or horizontally to regions of the atmosphere where such transformations are possible. Because DR reactions tend to be very exothermic, they can be an important source of kinetically or internally excited fragments. In interplanetary thermospheres, the neutral densities decrease exponentially with altitude. Below the homopause (or turbopause), the atmosphere is assumed to be throughly mixed by convection and/or turbulence. Above the homopause, diffusion is the major transport mechanism, and each species is distributed according to its mass, with the logarithmic derivative of the density with repect to altitude given approximately by -1/H, where H = kT/mg is the scale height. In this expression, T is the neutral temperature, g is the local acceleratiion of gravity, and m is the mass of the species. Thus lighter species become relatively more abundant, and heavier species less abundant, as the altitude increases. This variation of the neutral composition can lead to changes in the ion composition; furthermore, as the neutral densities decrease, dissociative recombination becomes more important relative to ion-neutral reactions as a loss mechanism for molecular ions.
    Keywords: GEOPHYSICS
    Type: ; fe sciences and spac
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  • 5
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    In:  Other Sources
    Publication Date: 2019-07-12
    Description: The vibrational distributions of O2(+) in the X2Pi(g), A2Pi(u), a4Pi(u), and b4Sigma(-)g states in the dayside terrestrial ionosphere are calculated for both low and high solar activity models. The distributions are found to be significantly different from the O2(+) vibrational distributions found by Fox (1985) for the Venusian ionosphere. The sources and sinks of vibrational excitation and the implications for the chemistry, dayglow, and hot oxygen coronas are discussed. Finally, intensities of the first negative and second negative band systems of O2(+) are presented.
    Keywords: GEOPHYSICS
    Type: Planetary and Space Science (ISSN 0032-0633); 34; 1241-125
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  • 6
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    In:  Other Sources
    Publication Date: 2019-07-12
    Description: The Ar(+) densities in the terrestrial ionosphere are computed for both low and high solar activity models. The reaction N2(+)(v greater than 0) + Ar yields N2 + Ar(+) is found to be a significant source of Ar(+) nearly equal to photoionization and electron impact ionization in the high solar activity model. Peak densities of Ar(+) of 11 per cu cm near 190 km and 22 per cu cm near 220 km are predicted for the low and high solar activity models. It is suggested that a simultaneous measurement of Ar(+) and Ar densities would provide a test for the presence of vibrationally excited N2(+) in the terrestrial ionosphere.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 91; 1731-173
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