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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 1 (1984), S. 403-428 
    ISSN: 1573-0662
    Keywords: prebiotic atmosphere ; oxygen levels ; carbon dioxide levels ; surface temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract One-dimensional radiative-convective and photochemical models are used to examine the effects of enhanced CO2 concentrations on the surface temperature of the early Earth and the composition of the prebiotic atmosphere. Carbon dioxide concentrations of the order of 100–1000 times the present level are required to compensate for an expected solar luminosity decrease of 25–30%, if CO2 and H2O were the only greenhouse gases present. The primitive stratosphere was cold and dry, with a maximum H2O volume mixing ratio of 10−6. The atmospheric oxidation state was controlled by the balance between volcanic emission of reduced gases, photo-stimulated oxidation of dissolved Fe+2 in the oceans, escape of hydrogen to space, and rainout of H2O2 and H2CO. At high CO2 levels, production of hydrogen owing to rainout of H2O2 would have kept the H2 mixing ratio above 2×10−4 and the ground-level O2 mixing ratio below 10−11, even if no other sources of hydrogen were present. Increased solar UV fluxes could have led to small changes in the ground-level mixing ratios of both O2 and H2.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2011-08-19
    Description: Large asteroid impacts produced globally lethal conditions by evaporating large volumes of ocean water on the early earth. The earth may have been continuously habitable by ecosystems that did not depend on photosynthesis as early as 4.44 Gyr BP (before present). Only a brief interval after 3.8 Gyr exists between the time when obligate photosynthetic organisms could continuously evolve and the time when the palaeontological record indicates highly evolved photosynthetic ecosystems.
    Keywords: GEOPHYSICS
    Type: Nature (ISSN 0028-0836); 342; 139-142
    Format: text
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  • 3
    Publication Date: 2011-08-19
    Description: The simulation of the sulfur cycle in the marine atmosphere using a one-dimensional photochemical model is described and evaluated. Theoretical uncertainties concerning the operation of the marine sulfur cycle are examined, and measurements of sulfur gases in the marine atmosphere necessary for developing the model are derived. Previous modeling studies are reviewed, and the data from these studies are compared to the model simulations. Recommendations for improving the simulation of the sulfur cycle in the marine atmosphere are discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 92; 943-963
    Format: text
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  • 4
    Publication Date: 2011-08-19
    Description: The possible consequences of very high carbon dioxide concentrations in the earth's early atmosphere have been investigated with a radiative-convective climate model. The early atmosphere would apparently have been stable against the onset of a runaway greenhouse (that is, the complete evaporation of the oceans) for carbon dioxide pressures up to at least 100 bars. A 10- to 20-bar carbon dioxide atmosphere, such as may have existed during the first several hundred million years of the earth's history, would have had a surface temperature of approximately 85 to 110 C. The early stratosphere should have been dry, thereby precluding the possibility of an oxygenic prebiotic atmosphere caused by photodissociation of water vapor followed by escape of hydrogen to space. Earth's present atmosphere also appears to be stable against a carbon dioxide-induced runaway greenhouse.
    Keywords: GEOPHYSICS
    Type: Science (ISSN 0036-8075); 234; 1383-138
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  • 5
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    Unknown
    In:  Other Sources
    Publication Date: 2019-06-28
    Description: It is shown that the faint young sun problem was most likely solved by an increase in atmospheric CO2 concentration in the earth's atmosphere brought about by the CO2 geochemical cycle. Because the loss process for atmospheric CO2 requires liquid water, and because the earth is continually resupplying atmospheric CO2 by carbonate metamorphism, the surface temperature should never have fallen below the point at which the ocean would freeze. Indeed, the early earth may have been quite warm if carbonate metamorphism was faster and if the continents were originally smaller, so that silicate weathering was inhibited.
    Keywords: GEOPHYSICS
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  • 6
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2019-08-28
    Description: The volume of earth's oceans may be determined by a dynamic mechanism involving exchange of water between the crust and the mantle. Fast-spreading mid-ocean ridges are currently submerged to a depth at which the pressure is close to the critical pressure for seawater. This ensures optimal convective heat transport and, hence, maximal penetration of hydrothermal circulation along the ridge axes. The oceanic crust is hydrated to a depth of a kilometer or more and can therefore carry a substantial flux of water to the upper mantle when it is subducted. The current ingassing rate of water by this process is probably at least sufficient to balance the outgassing rate. If the oceans were shallower, as they may have been in the distant past, convective heat transport would be reduced and the depth of hydrothermal penetration and crustal hydration would decrease. Outgassing would exceed ingassing and ocean volume would increase. The system is self-stabilizing as long as the depth of the oceans does not exceed its present value. This mechanism could explain why continental freeboard has remained approximately constant since the Archean despite probable increases in continental area.
    Keywords: GEOPHYSICS
    Type: Earth and Planetary Science Letters (ISSN 0012-821X); 109; 3-4,; 507-515
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  • 7
    Publication Date: 2019-07-12
    Description: A one-dimensional model is utilized to study the role of nonmethane hydrocarbons (NMHCs) in tropospheric chemistry. The effects of NMHCs on tropospheric peroxyacetyl nitrate (PAN) formation are analyzed; the global distribution and seasonal variability of PAN in the troposphere of the Northern and Southern Hemispheres are examined. The NMHC-PAN measurements obtained by model simulations are compared to the photochemical theory. The seasonal cycles in NMHC abundances are predicted, and their effects on other tropospheric species are investigated.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 91; 13239-13
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  • 8
    Publication Date: 2019-07-12
    Description: A one-dimensional photochemical model was used to examine the effect of bolide impacts on the oxidation state of earth's primitive atmosphere. The impact rate should have been high prior to 3.8 Ga before present, based on evidence derived from the moon. Impacts of comets or carbonaceous asteroids should have enhanced the atmospheric CO/CO2 ratio by bringing in CO ice and/or organic carbon that can be oxidized to CO in the impact plume. Ordinary chondritic impactors would contain elemental iron that could have reacted with ambient CO2 to give CO. Nitric oxide (NO) should also have been produced by reaction between ambient CO2 and N2 in the hot impact plumes. High NO concentrations increase the atmospheric CO/CO2 ratio by increasing the rainout rate of oxidized gases. According to the model, atmospheric CO/CO2 ratios of unity or greater are possible during the first several hundred million years of earth's history, provided that dissolved CO was not rapidly oxidized to bicarbonate in the ocean.
    Keywords: GEOPHYSICS
    Type: Origins of Life and Evolution of the Biosphere (ISSN 0169-6149); 20; 4-Mar
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