ISSN:
0009-2940
Keywords:
Ethylene-bridged metal complexes
;
Ethanediyl complexes
;
Manganese, Rhenium, Ruthenium, Osmium carbonyls
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydrocarbon-Bridged Metal complexes, XVIII. - Heterometallic Ethylene-Bridged Complexes (OC)5ReCH2CH2Mn(CO)5, (OC)5ReCH2CH2Ru(CO)2Cp, (OC)5ReCH2CH2Os(CO)4CH2CH2Re(CO)5 and (OC)5ReCH2CH2CH2Os(CO)4Os(CO)4(CO)4Os(CO)4CH2CH2Re(CO)5Addition of [(OC)5Re(C2H4)]+ to the carbonylmetallates [Mn(CO)5]-, [RuCp(CO)2]-, [Os(CO)4]2-, [Os3(CO)12]2- affords the title complexes in a directed way. The dynamic behaviour of (OC)5ReCH2CH2Mn(CO)5 in solution is attributed to a dyotropic exchange of the pentacarbonylmetal groups on the CH2CH2 bridge.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240512
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