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  • Inorganic Chemistry  (12)
  • Hypoxia  (3)
  • Estuaries  (2)
  • 1
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 6392-6407, doi:10.1029/2018JC014129.
    Description: Low levels of dissolved oxygen (DO) occur in many embayments throughout the world and have numerous detrimental effects on biota. Although measurement of in situ DO is straightforward with modern instrumentation, quantifying the volume of water in a given embayment that is hypoxic (hypoxic volume (HV)) is a more difficult task; however, this information is critical for determining whether management efforts to increase DO are having an overall impact. This paper uses output from a three‐dimensional numerical model to demonstrate that HV in Chesapeake Bay can be estimated well with as few as two vertical profiles. In addition, the cumulative hypoxic volume (HVC; the total amount of hypoxia in a given year) can be calculated with relatively low uncertainty (〈10%) if continuous DO data are available from two strategically positioned vertical profiles. This is because HV in the Chesapeake Bay is strongly constrained by the geometry of the embayment. A simple Geometric HV calculation method is presented and numerical model results are used to illustrate that for calculating HVC, the results using two daily‐averaged profiles are typically more accurate than those of the standard method that interpolates bimonthly cruise data. Bimonthly data produce less accurate estimates of HVC because high‐frequency changes in oxygen concentration, for example, due to regional‐weather‐ or storm‐induced changes in wind direction and magnitude, are not resolved. The advantages of supplementing cruise‐based sampling with continuous vertical profiles to estimate HVC should be applicable to other systems where hypoxic water is constrained to a specific area by bathymetry.
    Description: NOAA Grant Number: NA13NOS0120139
    Keywords: Chesapeake Bay ; Oxygen ; Dead zone ; Hypoxia ; Observing systems ; Estuary
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 118 (2013): 6319–6328, doi:10.1002/2013JC008939.
    Description: Strong and strategic collaborations among experts from academia, federal operational centers, and industry have been forged to create a U.S. IOOS Coastal and Ocean Modeling Testbed (COMT). The COMT mission is to accelerate the transition of scientific and technical advances from the coastal and ocean modeling research community to improved operational ocean products and services. This is achieved via the evaluation of existing technology or the development of new technology depending on the status of technology within the research community. The initial phase of the COMT has addressed three coastal and ocean prediction challenges of great societal importance: estuarine hypoxia, shelf hypoxia, and coastal inundation. A fourth effort concentrated on providing and refining the cyberinfrastructure and cyber tools to support the modeling work and to advance interoperability and community access to the COMT archive. This paper presents an overview of the initiation of the COMT, the findings of each team and a discussion of the role of the COMT in research to operations and its interface with the coastal and ocean modeling community in general. Detailed technical results are presented in the accompanying series of 16 technical papers in this special issue.
    Description: This project was supported by NOAA via the IOOS Office, award NA10NOS0120063 and NA11NOS0120141, and used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by National Science Foundation grant OCI- 1053575.
    Keywords: Modeling ; Hypoxia ; Inundation ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 118 (2013): 4924–4944, doi:10.1002/jgrc.20331.
    Description: The overall size of the “dead zone” within the main stem of the Chesapeake Bay and its tidal tributaries is quantified by the hypoxic volume (HV), the volume of water with dissolved oxygen (DO) less than 2 mg/L. To improve estimates of HV, DO was subsampled from the output of 3-D model hindcasts at times/locations matching the set of 2004–2005 stations monitored by the Chesapeake Bay Program. The resulting station profiles were interpolated to produce bay-wide estimates of HV in a manner consistent with nonsynoptic, cruise-based estimates. Interpolations of the same stations sampled synoptically, as well as multiple other combinations of station profiles, were examined in order to quantify uncertainties associated with interpolating HV from observed profiles. The potential uncertainty in summer HV estimates resulting from profiles being collected over 2 weeks rather than synoptically averaged ∼5 km3. This is larger than that due to sampling at discrete stations and interpolating/extrapolating to the entire Chesapeake Bay (2.4 km3). As a result, sampling fewer, selected stations over a shorter time period is likely to reduce uncertainties associated with interpolating HV from observed profiles. A function was derived that when applied to a subset of 13 stations, significantly improved estimates of HV. Finally, multiple metrics for quantifying bay-wide hypoxia were examined, and cumulative hypoxic volume was determined to be particularly useful, as a result of its insensitivity to temporal errors and climate change. A final product of this analysis is a nearly three-decade time series of improved estimates of HV for Chesapeake Bay.
    Description: Funding for this study was provided by the IOOS COMT Program through NOAA grants NA10NOS0120063 and NA11NOS0120141. Additional funding was provided by NSF grant OCE-1061564.
    Keywords: Hypoxia ; Hypoxic volume ; Chesapeake Bay ; Dead zone ; Water quality ; Dissolved oxygen
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 116 (1983), S. 2344-2354 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Host-Guest Compounds of Macrocyclic Host Molecules with Water, Xylene, and DioxaneThe preparation and X-ray structural investigation of the three stoichiometric host-guest compounds 1·2 H2O, 2·xylene and 3·3 dioxane, is described. Whereas the tetralactame cryptand host 1 with water forms hydrogen bridges using its carbonyl oxygen atoms, leading to chain type arrangement in the crystal, the para-xylene adduct of cryptand 2 and the dioxane adduct of the tetraazaphane 3 both are channel type inclusions of the guest molecules in the host lattice. It is concluded that even if an approximate geometric fit of a guest to the host cavity is given, the alternative of a lattice inclusion nevertheless may be favoured.
    Notes: Darstellung und die durch Röntgenstrukturanalyse geklärten räumlichen Verhältnisse der stöchiometrischen Wirt/Gast-Verbindungen 1·2H2O, 2·Xylol und 3·3 Dioxan im Kristallgitter werden beschrieben. Während der Tetracarbonsäuretetraamid-Cryptandwirt 1 mit Wasser über H-Brückenbindungen zu den Carbonylgruppen kettenartige Strukturen bildet, findet man für das Xylol-Addukt des Cryptanden 2 und für das Dioxan-Addukt des Tetraaza-phans 3 kanalartige Anordnungen der Lösungsmittelmoleküle im Wirtgitter. Es wird die Schlußfolgerung gezogen, daß auch bei räumlich annähernd ineinander passender Wirt/Gastmolekül-Topologie nicht zwangsläufig molekulare, sondern oft Gitter-Einschlüsse zustandekommen.
    Additional Material: 2 Ill.
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  • 5
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Helical Molecules, IX. Syntheses, Enantiomer Separations, Circular Dichroism, Racemization Barriers, X-Ray Analyses, and Absolute Conformations of New, Easily Available ArenicenesThe new helical compounds 1-3 have been synthesized. 1 and 2 are separated into the enantiomers by chromatography on cellulose triacetate. The rotatory powers are high: e.g., [α]43620 = 2096 for 1. The racemization/ring inversion barriers range between 115 and 125 kJ/mol. X-ray analyses of 1-3 reveal different torsional angles between the rings ABC from 3.6 to 10.4°. They are compensated through the different interplanar angles of A and C with the plane B in such a way that the distance d between the intraanular C-Atoms in all compounds 1-4 is similar (2.57-2.60 Å). Correspondingly, the δ(Hi) values of 1-4 are found to differ only slightly (5.32-5.67 ppm). A determination of the absolute conformation using Bijvoets method shows (-)-2 (λ = 546 nm) to be the P-helix, and ( + )-2 the M-helix.
    Notes: Die neuen helicalen Verbindungen 1-3 werden synthetisiert, 1 und 2 durch Chromatographie an Triacetylcellulose in die Enantiomeren getrennt. Die optischen Drehungen sind hoch: z. B. [α]43620 = 2096 für 1. Die Racemisierungs-/Ringinversionsbarrieren liegen zwischen 115 und 125 kJ/mol. Röntgenstrukturanalysen von 1-3 ergeben unterschiedliche Torsionswinkel zwischen den Ringen ABC von 3.6-10.4°. Sie werden durch die unterschiedlichen Interplanarwinkel von A und C mit der Ebene B derart kompensiert, daß der Abstand d zwischen den intraanularen C-Atomen bei allen Verbindungen 1-4 nahezu gleich ist (2.57-2.60 Å). Entsprechend wird auch für δ(Hi) von 1-4 eine nur geringfügig variierende Verschiebung von 5.32-5.67 ppm gefunden. Die Bestimmung der absoluten Konformation nach der Bijvoet-Methode ergab für (-)-2 (λ = 546 nm) die P-, für ( + )-2 die M-Helix-Struktur.
    Additional Material: 2 Ill.
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  • 6
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Heterocyclic β-Enamino Esters, 40. About Dimerizates and Trimerizates of 2-Amino-3-cyano-4,5-dihydrofurans in Formamide. X-ray Analysis of a 4,4-Bis(furo[2,3-d]pyrimidin-2-yl)-2-butanolUpon heating in formamide the 2-amino-3-cyano-4,5-dihydrofurans 1a-c undergo dimerization reaction to 2-(furan-3-ylidene)furo[2,3-d]pyrimidines 3a-c; additionally, a novel trimerization reaction to the 4,4-bis(furo[2,3-d]pyrimidin-2-yl)-2-butanols 4b-e is observed. The structure of 4d is established by X-ray diffraction.
    Notes: Die 2-Amino-3-cyan-4,5-dihydrofurane 1a-c dimerisieren beim Erhitzen in Formamid zu den 2-(Furan-3-yliden)furo[2,3-d]pyrimidinen 3a-c; daneben findet eine neuartige Trimerisierung zu 4,4-Bis(furo[2,3-d]pyrimidin-2-yl)-2-butanolen 4b-e statt. Die Konstitution von 4d wird durch Röntgenstrukturanalyse ermittelt.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 127 (1923), S. 221-227 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Der Schmelzpunkt des reinen Hydrazins wurde dilatometrisch mit + 1,8° festgelegt.
    Additional Material: 3 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 127 (1923), S. 228-228 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 84 (1913), S. 373-400 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Es wurde eine Systematik binärer Systeme unter Berücksichtigung der kritischen Erscheinungen aufgestellt.
    Additional Material: 11 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 116 (1921), S. 141-160 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 11 Ill.
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