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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 20 (1993), S. 645-650 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A calculation method for the secondary ion mass spectrometry (SIMS) analysis of the reaction of a pure metal with gas mixtures of water and oxygen is introduced. Equation systems are to be solved, each expressed as: Y = A × X, where Y is an amplitude column measured from the SIMS spectrum, A is a matrix constructed from the relative abundances of isotopes of the metal and X is an unknown amplitude column of the relevant species MeaOHb±(a = 1, 2; b = 0, 1, 2 and 3). The applicability of the calculation method has been tested in SIMS analysis of ex situ-grown iron oxides with different and known 18O contents. In in situ oxidation, measurement of the ratio of H216O/H218O in the metal-water-oxygen reaction allows fractions of O in the species MeaOHb+ that originate from water to be calculated. Data from such calculations have been used to study the initial stage of the reaction of Fe and Cr in H216O/H218O/16O2 gas mixtures. The results are interpreted in terms of coupled/uncoupled reaction type, reactivity of metal to water relative to oxygen in the mixed gas and degree of dissociation of water.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 21 (1994), S. 800-804 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Iron oxide films with known 18O and 16O content were prepared by thermal oxidation of iron metal in H218O/H216O gas mixtures at 400°C. The oxide films were analysed in four laboratories with SIMS within a month after they were produced. One oxide sample (with 91% 18O) was also analysed after storage in air for 15 months. It turns out that the oxides are stable over that time period. The yield ratios of the detected ionic species based on negative 18O and 16O ions and metal-oxygen-containing ions were compared with the nominal, known values. The effect of interference of residual 16O and 16OH on the results is discussed and appropriate measures for reducing this effect are proposed. Reasonably good agreement is found between the four laboratories.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 13 (1991), S. 1055-1070 
    ISSN: 0271-2091
    Keywords: Matched asymptotic expansion ; Solitary wave ; Shallow water waves ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the present paper, limited to the discussion of weak non-linear shallow water waves, the transmission and reflection of a planar soliton on a two-dimensional structure are considered. The whole flow field is divided mainly into two subfields. One is in the vicinity of the structure, called the inner field; the other is far from the structure, called the outer field. In the outer field, according to its definition, the influence of the structure on the flow is negligible; to the order O(α, β) the governing equation for the flow is replaced by the Boussinesq equation. In the inner field the effect of the structure on the flow is significant, so the full Laplace equation is adopted as the governing equation for the flow field. Then the matched asymptotic expansion method is employed to connect smoothly the inner and outer solutions. Owing to the irregularity of the bottom of the structure, the boundary element method is incorporated. As an example, the case in which the incoming wave is a solitary wave is calculated and the time histories of transmitted and reflected waves are plotted.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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