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  • Eluent composition effects  (1)
  • anaerobic sediment  (1)
  • benthic organism  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 317 (1996), S. 31-40 
    ISSN: 1573-5117
    Keywords: benthic organism ; diffusion ; mixing ; sediments ; tritium ; transport
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Increased inputs of nutrients into the waters of Lake Okeechobee has raised concern that the lake is becoming hypereutrophic. One aspect in understanding the overall cycling and dynamics of the nutrients in the system is the effect of benthic organisms on solute transport. Various diffusional models have been used to approximate the effect of benthic organisms on solute transport within sediments using diffusion coefficient values which represent the pooled contributions of molecular diffusion (D s ) and enhanced solute mixing due to macrobenthos activity (D i ). The objective of this study was to investigate the impact of benthic activity on solute transport by measuringD s (i.e., no benthic activity) and an apparent-dispersion or mixing coefficientD m (i.e., with benthic activity) for the four major sediment types of Lake Okeechobee, Florida using a reservoir technique. This method involved monitoring the depletion of a conservative tracer (tritiated water) from the overlying water (reservoir) resulting from transport into sediments using disturbed sediments repacked in cores (3.2 cm diam.) and undisturbed cores (3.2 to 12 cm diam.) obtained from the lake. Additional estimates ofD m andD s were also obtained by measuring tracer concentration profiles in the sediment cores at the end of a specified diffusion period. Molecular diffusion coefficients (D s ) measured forrepacked cores of sand, littoral, mud and peat sediments ranged from 0.90 to 1.29 cm2 d−1, and estimates ofD s were slightly higher in undisturbed cores without benthic organisms.D m values for undisturbed cores of mud, sand and littoral sediments having macrobenthic populations ranged from 2.09 to 24.78 cm2 d−1; values that were 1.6 to 15 times higher than those in sediments without benthic activity. Undisturbed cores of varying diameter from mud sediments had similar estimates ofD m for tritium; however, the undisturbed cores with larger diameters from littoral sediments yielded larger estimates ofD m , reflecting the heterogeneity of benthic population densities and activity. Therefore,D s estimates may not adequately represent transport processes for mud, sand and littoral sediments of Lake Okeechobee; hence careful consideration should be given to the role of benthic organisms in the overall transport of solutes across the sediment-water interface.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 159 (1988), S. 177-188 
    ISSN: 1573-5117
    Keywords: eutrophic lake water ; nitrogen flux ; anaerobic sediment ; simulation model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Nitrogen flux from sediment of a shallow lake and subsequent utilization by water hyacinth (Eichhornia crassipes [Mart] Solms) present in the water column were evaluated using an outdoor microcosm sediment-water column. Sediment N was enriched with 15N to quantitatively determine the movement of NH4-N from the sediment to the overlying water column. During the first 30 days. 48% of the total N uptake by water hyacinth was derived from sediment 15NH4-N. This had decreased to 14% after 183 days. Mass balance of N indicates that about 25% sediment NH4-N was released into the overlying water, but only 17% was assimilated by water hyacinth. NH4-N levels in the water column were very low, with very little or no concentration gradients. NH4-N levels in the interstitial water of the sediment were in the range of 30–35 mg L−1 for the lower depths (〉 35 cm), while in the surface 5 cm of depth NH4-N levels decreased to 3.2 mg L−1. Simulated results also showed similar trends for the interstitial NH4-N concentration of the sediment. The overall estimated NH4-N flux from the sediment to the overlying water was 4.8 µg cm−2 day−1, and the soluble organic N flux was 5.8 µg N cm−2 day−1. Total N flux was 10.6 µg N cm−2 day−1.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Hydrophobic solutes ; Enthalpy and entropy changes ; Eluent composition effects ; Surface area effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Chromatographic retention of several nonpolar solutes by three reversed-phase liquid chromatography (RPLC) supports was measured at several temperatures with binary mixtures of methanol/water and acetonitrile/water as the mobile phase. These data were used to estimate enthalpy and entropy changes (ΔH sorp o and ΔS sorp o ) associated with solute retention. The dependence of these two thermodynamic parameters on organic solvent content (θ) in the mobile phase, solute hydrophobic surface area (HSA), and bonded n-alkyl chain length (Nc) of the RPLC support was evaluated. The differences noted in the two solvent mixtures were attributed to: (1) the manner in which solvent surface tension changes with increasing θ, and (2) the differences in the interaction of methanol and acetonitrile with the bonded alkyl chains.
    Type of Medium: Electronic Resource
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