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  • Eluent composition effects  (1)
  • adaptive capacity  (1)
  • anaerobic sediment  (1)
  • 1
    Publication Date: 2021-10-15
    Description: Cities are the drivers of socioeconomic innovation and are also forced to address the accelerating risk of failure in providing essential services such as water supply today and in the future. Here, we investigate the resilience of urban water supply security, which is defined in terms of the services that citizens receive. The resilience of services is determined by the availability and robustness of critical system elements or “capitals” (water resources, infrastructure, finances, management efficacy, and community adaptation). We translate quantitative information about this portfolio of capitals from seven contrasting cities on four continents into parameters of a coupled system dynamics model. Water services are disrupted by recurring stochastic shocks, and we simulate the dynamics of impact and recovery cycles. Resilience emerges under various constraints, expressed in terms of each city's capital portfolio. Systematic assessment of the parameter space produces the urban water resilience landscape, and we determine the position of each city along a continuous gradient from water insecure and nonresilient to secure and resilient systems. In several cities stochastic disturbance regimes challenge steady-state conditions and drive system collapse. While water insecure and nonresilient cities risk being pushed into a poverty trap, cities which have developed excess capitals risk being trapped in rigidity and crossing a tipping point from high to low services and collapse. Where public services are insufficient, community adaptation improves water security and resilience to varying degrees. Our results highlight the need for resilience thinking in the governance of urban water systems under global change pressures.
    Keywords: 333.9 ; systems dynamics modeling ; coupled natural-human-engineered systems (CNHES) ; adaptive capacity ; water management ; stochastic shocks ; Capital Portfolio Approach (CPA)
    Language: English
    Type: map
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 159 (1988), S. 177-188 
    ISSN: 1573-5117
    Keywords: eutrophic lake water ; nitrogen flux ; anaerobic sediment ; simulation model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Nitrogen flux from sediment of a shallow lake and subsequent utilization by water hyacinth (Eichhornia crassipes [Mart] Solms) present in the water column were evaluated using an outdoor microcosm sediment-water column. Sediment N was enriched with 15N to quantitatively determine the movement of NH4-N from the sediment to the overlying water column. During the first 30 days. 48% of the total N uptake by water hyacinth was derived from sediment 15NH4-N. This had decreased to 14% after 183 days. Mass balance of N indicates that about 25% sediment NH4-N was released into the overlying water, but only 17% was assimilated by water hyacinth. NH4-N levels in the water column were very low, with very little or no concentration gradients. NH4-N levels in the interstitial water of the sediment were in the range of 30–35 mg L−1 for the lower depths (〉 35 cm), while in the surface 5 cm of depth NH4-N levels decreased to 3.2 mg L−1. Simulated results also showed similar trends for the interstitial NH4-N concentration of the sediment. The overall estimated NH4-N flux from the sediment to the overlying water was 4.8 µg cm−2 day−1, and the soluble organic N flux was 5.8 µg N cm−2 day−1. Total N flux was 10.6 µg N cm−2 day−1.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Hydrophobic solutes ; Enthalpy and entropy changes ; Eluent composition effects ; Surface area effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Chromatographic retention of several nonpolar solutes by three reversed-phase liquid chromatography (RPLC) supports was measured at several temperatures with binary mixtures of methanol/water and acetonitrile/water as the mobile phase. These data were used to estimate enthalpy and entropy changes (ΔH sorp o and ΔS sorp o ) associated with solute retention. The dependence of these two thermodynamic parameters on organic solvent content (θ) in the mobile phase, solute hydrophobic surface area (HSA), and bonded n-alkyl chain length (Nc) of the RPLC support was evaluated. The differences noted in the two solvent mixtures were attributed to: (1) the manner in which solvent surface tension changes with increasing θ, and (2) the differences in the interaction of methanol and acetonitrile with the bonded alkyl chains.
    Type of Medium: Electronic Resource
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