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  • Electron density  (1)
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    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 25 (1995), S. 653-656 
    ISSN: 1572-8854
    Keywords: Electron density ; thiols ; HDS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the [CpRu(PPh3)2(C6H11SH)]BF4·CH2Cl2 complex was determined by X-ray diffraction techniques; triclinic space group $$P\bar 1$$ ,a=12.567(1),b=13.409(1),c=14.733(1) Å, α=95.380(7), β=111.041(7), γ=96.454(8)°,V=2278.5(4) Å3,Z=2,R=0.056,R w=0.088. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the S atom of the cyclohexylthiol. The Ru−S distance is 2.389(2) Å and the S−H distance is 1.23 Å.
    Type of Medium: Electronic Resource
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