ISSN:
1434-193X
Schlagwort(e):
Cyclam
;
PEO
;
Nickel
;
Electrochemistry
;
Macrocyclic compound
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
A specific strategy is described for the synthesis of stable polyethylene oxide tagged tetraazamacrocycles (PEO-cyclam) in five steps (overall yields for 12 and 13 48% and 22%, respectively). Various attempts via classical pathways demonstrated: (i) the low reactivity of PEO derivatives, and (ii) the necessity of a stabiliser arm between the cyclam and the PEO chain. Nickel complexes have been prepared and characterised by electrochemistry.
Zusätzliches Material:
1 Tab.
Materialart:
Digitale Medien
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