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  • East Pacific Rise  (1)
  • Molecular iodine  (1)
  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © National Shellfisheries Association, 2008. This article is posted here by permission of National Shellfisheries Association for personal use, not for redistribution. The definitive version was published in Journal of Shellfish Research 27 (2008): 169-175, doi:10.2983/0730-8000(2008)27[169:HVMHCP]2.0.CO;2.
    Description: Between October 2005 and March 2006, a seafloor volcanic eruption occurred at 9°50′N East Pacific Rise (EPR), establishing a “time zero” for characterizing newly-formed hydrothermal vent habitats and comparing them to pre-eruption habitats. Before the eruption, mussels (Bathymodiolus thermophilus) formed large aggregates between 9°49.6′ and 9°50.3′N. After the eruption, the few mussels remaining were in sparsely-distributed individuals and clumps, seemingly transported via lava flows or from mass wasting of the walls of the axial trough. In situ voltammetry with solid state gold-amalgam microelectrodes was used to characterize the chemistry of vent fluids in mussel habitats from 2004 to 2007, providing data sets for comparison of oxygen, sulfide, and temperature. Posteruption fluids contained higher sulfide-to-temperature ratios (i.e., slopes of linear regressions) (10.86 μM °C−1) compared with pre-eruption values in 2004 and 2005 (2.79 μM °C−1 and −0.063 μM °C−1, respectively). These chemical differences can be attributed to the difference in geographic location in which mussels were living and physical factors arising from posteruptive fluid emissions.
    Description: This work was funded by NSF grants OCE- 0327353 (RAL and CV), OCE-0327261 and OCE-0451983 (TS), OCE-0326434 and OCE-0308398 (GWL).
    Keywords: Bathymodiolus thermophilus ; East Pacific Rise ; Hydrothermal vent ; In situ electrochemistry ; Mussels ; Oxygen ; Sulfide
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Aquatic geochemistry 1 (1995), S. 89-104 
    ISSN: 1573-1421
    Keywords: Molecular iodine ; iodination kinetics ; iodine speciation ; organic iodine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The reactivity of 2 µM molecular iodine in seawater toward various organic compounds containing aromatic, α-keto, amino, olefinic and sugar functional groups was investigated. More detailed studies have been made of the reduction kinetics with salicylic acid, α-ketoglutaric acid and the polypeptide oxidized glutathione, particularly to establish whether variation over the pH range 4–9 would provide a similar reduction reactivity or “fingerprint” to that of molecular iodine added to natural seawater. The data indicates that compounds with only one functional group react with first order kinetics whereas compounds with multiple functional groups show more complex behaviour. Kinetic and thermodynamic modelling indicates that HOI is the main iodine species reacting with organic matter at seawater pH of 8.2. Based on the pH “fingerprints”, peptides and compounds containing carbonyl or α-keto groups are the key reductants of molecular iodine added to seawater. These compounds form C-I and N-I bonds which can allow for a rich organic iodine chemistry in seawater. The model compound results are discussed in relation to oceanic processes.
    Type of Medium: Electronic Resource
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