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  • 1
    Publication Date: 2023-07-20
    Description: The major-element chemical composition of garnet provides valuable petrogenetic information, particularly in metamorphic rocks. When facing detrital garnet, information about the bulk-rock composition and mineral paragenesis of the initial garnet-bearing host-rock is absent. This prevents the application of chemical thermo-barometric techniques and calls for quantitative empirical approaches. Here we present a garnet host-rock discrimination scheme that is based on a random forest machine-learning algorithm trained on a large dataset of 13,615 chemical analyses of garnet that covers a wide variety of garnet-bearing lithologies. Considering the out-of-bag error, the scheme correctly predicts the original garnet host-rock in (i) 〉 95% concerning the setting, that is either mantle, metamorphic, igneous, or metasomatic; (ii) 〉 84% concerning the metamorphic facies, that is either blueschist/greenschist, amphibolite, granulite, or eclogite/ultrahigh-pressure; and (iii) 〉 93% concerning the host-rock bulk composition, that is either intermediate–felsic/metasedimentary, mafic, ultramafic, alkaline, or calc–silicate. The wide coverage of potential host rocks, the detailed prediction classes, the high discrimination rates, and the successfully tested real-case applications demonstrate that the introduced scheme overcomes many issues related to previous schemes. This highlights the potential of transferring the applied discrimination strategy to the broad range of detrital minerals beyond garnet. For easy and quick usage, a freely accessible web app is provided that guides the user in five steps from garnet composition to prediction results including data visualization.
    Description: deutsche forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Georg-August-Universität Göttingen (1018)
    Description: http://134.76.17.86:443/garnetRF/
    Keywords: ddc:549 ; Garnet major-element composition ; Database ; Host-rock discrimination ; Machine-learning ; Provenance ; Web app
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2021-03-29
    Description: Investigation by Raman spectroscopy of samples from different geological settings shows that the occurrence of TiO2 polymorphs other than rutile can hardly be predicted, and furthermore, the occurrence of anatase is more widespread than previously thought. Metamorphic pressure and temperature, together with whole rock chemistry, control the occurrence of anatase, whereas variation of mineral assemblage characteristics and/or fluid occurrence or composition takes influence on anatase trace element characteristics and re-equilibration of relict rutiles. Evaluation of trace element contents obtained by electron microprobe in anatase, brookite, and rutile shows that these vary significantly between the three TiO2 phases. Therefore, on the one hand, an appropriation to source rock type according to Nb and Cr contents, but as well application of thermometry on the basis of Zr contents, would lead to erroneous results if no phase specification is done beforehand. For the elements Cr, V, Fe, and Nb, variation between the polymorphs is systematic and can be used for discrimination on the basis of a linear discriminant analysis. Using phase group means and coefficients of linear discriminants obtained from a compilation of analyses from samples with well-defined phase information together with prior probabilities of groupings from a natural sample compilation, one is able to calculate phase grouping probabilities of any TiO2 analysis containing at least the critical elements Cr, V, Fe, and Nb. An application of this calculation shows that for the appropriation to the phase rutile, a correct-classification rate of 99.5% is obtained. Hence, phase specification by trace elements proves to be a valuable tool besides Raman spectroscopy.
    Keywords: TiO2 polymorph discrimination; Phase classification; Anatase; Brookite; Rutile; Erzgebirge; Zr-in-rutile thermometry ; 551 ; Earth Sciences; Mineral Resources; Mineralogy; Geology
    Language: English
    Type: article , publishedVersion
    Format: application/pdf
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