ISSN:
1572-879X
Keywords:
ESR
;
selective oxidation
;
copper-catalysis
;
zeolite
;
ethane
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Catalytic ethane oxidation, with O2, using H-ZSM-5 and H-mordenite containing different discrete types of isolated Cu(II) cations was studied. An ESR spectroscopic study was carried out on copper ion coordination in zeolites. It was shown that the intrinsic activity of Cu(II) ion depends strongly on the Cu2+-site local topography. Covalent-bonded Cu(II) cations in the most coordinatively unsaturated square-planar coordination in H-ZSM-5 demonstrated the highest activity in C2H6 complete oxidation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00772083
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