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  • Drygelatinfilms  (1)
  • multilayer formation
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 268 (1990), S. 286-289 
    ISSN: 1435-1536
    Keywords: Drygelatinfilms ; structure ; surfactants ; conoscopicray
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The interference image of cold-dried transparent gelatin films containing different surfactants was determined in the conoscopic ray of monochromatic light. From the results obtained the order of the structure of gelatin in the film was characterized. Unlike the ionic surfactants (sodium dodecyl sulfate and hexadecyltrimethyl ammonium bromide), which lead to a reduction of the ordered structure, the addition of nonionic and amphoteric surfactants [ethoxylized octylphenole and a technical C12/C14-dipoly(oxyethylene)ammoniopropane sulfonate] causes an increase of the ordered structure of gelatin. The results quantitatively agree with those found for the influence of surfactants on the secondary structure of gelatin in diluted gelatin solutions. The influence is independent of the gelatin/surfactant ratio and has been explained by gelatin/gelatin interaction competing with the gelatin/surfactant interaction if the gelatin concentration becomes sufficiently high.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 262 (1984), S. 821-826 
    ISSN: 1435-1536
    Keywords: Surface rheology ; adsorbed gelatin layers ; surface tension ; multilayer formation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Adsorbed gelatin layers have been characterized by measuring the surface equilibrium tension and surface rheological parameters of shear, found by surface creep experiments. After the determination of these parameters the solution below the adsorption layer (gelatin + phosphate buffer) was substituted by a gelatin-free phosphate-buffer-solution. The differences of the parameters calculated before and after the substitution of the bulk phase allowed us to prove some model assumptions of the protein adsorption and to characterize the physical contents of some of the surface rheological parameters determined. The parameters calculated and measured permit the distinction of three different concentration ranges of gelatin: 1) the range of reversible adsorption layer. 2) the ranges of saturated, irreversible adsorption layer, and 3) the range of multilayer formation.
    Type of Medium: Electronic Resource
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