ISSN:
1572-8854
Keywords:
ferrocene
;
dicarbaldehyde
;
layered structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The crystal and molecular structure of 1,1′-ferrocene-dicarbaldehyde 1 is reported. Crystal data for 1: monoclinic, space group P21/n, a = 5.876(1), b = 11.349(1), c = 29.460(3) Å,β = 95.067(2)°, V = 1956.9(3) Å3, and D c = 1.64 g/cm3, for Z = 8. The complex crystallizes such that two molecules are located in the asymmetric unit in which the complexes display different degrees of twisting of the cyclopentadienyl (Cp) rings and formyl substituents about the Cp—Fe—Cp and Cp—COH axes, respectively. The molecule self-assembles in the solid state to form a 2D layered structure held together by π-π interactions and C—H···O hydrogen bonds.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009568409349
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